[(η5-C5H4Me)MnH(CO)2B(C6F5)2]

Base Information

• Chemical Name: [(η5-C5H4Me)MnH(CO)2B(C6F5)2]
• CAS No.: 824426-53-1
• Molecular Formula: C₂₀H₈BF₁₀MnO₂
• Molecular Weight: 536.015
• Mol file: 824426-53-1.mol

Synonyms:

Chemical Property of [(η5-C5H4Me)MnH(CO)2B(C6F5)2]

Chemical Property:

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Useful:

Technology Process of [(η5-C5H4Me)MnH(CO)2B(C6F5)2]

There total 1 articles about [(η5-C5H4Me)MnH(CO)2B(C6F5)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

K{π-MeCp(CO)2MnH} + bis(pentafluorophenyl)boron chloride (2720-03-8) → [(η5-C5H4Me)MnH(CO)2B(C6F5)2] (824426-53-1)

Guidance literature:

In ⁽²⁾H₈-toluene; to suspn.K((C5H4Me)MnH(CO)2) in toluene-d8 at -50°C was added ClB(C6F5)2 in toluene-d8, agitation and warming to -30°C under inertatm.; identified by NMR;

DOI:10.1039/b414940h

Reference yield:

[(η5-C5H4Me)MnH(CO)2B(C6F5)2] (824426-53-1) + methyldiphenylsilane (776-76-1) → MeCp(CO)2Mn(H)SiPh2Me

Guidance literature:

In ⁽²⁾H₈-toluene; Irradiation (UV/VIS); to soln. (C5H4Me)MnH(CO)2B(C6F5)2 in toluene-d8 was added excess SiPh2Meat -30°C under inert atm., photolysis for 12 h at -30°C; NMR monitoring;

DOI:10.1039/b414940h

upstream raw materials:

bis(pentafluorophenyl)boron chloride