tricarbonyl(3-phenyl-2-[(pyridine-3-carbonyl)amino]propionic acid methyl ester)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

Base Information

• Chemical Name: tricarbonyl(3-phenyl-2-[(pyridine-3-carbonyl)amino]propionic acid methyl ester)(1,10-phenanthroline)rhenium(I) hexafluorophosphate
• CAS No.: 1312104-85-0
• Molecular Formula: C₃₁H₂₄N₄O₆Re*F₆P
• Molecular Weight: 879.726
• Mol file: 1312104-85-0.mol

Synonyms:

Chemical Property of tricarbonyl(3-phenyl-2-[(pyridine-3-carbonyl)amino]propionic acid methyl ester)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of tricarbonyl(3-phenyl-2-[(pyridine-3-carbonyl)amino]propionic acid methyl ester)(1,10-phenanthroline)rhenium(I) hexafluorophosphate

There total 1 articles about tricarbonyl(3-phenyl-2-[(pyridine-3-carbonyl)amino]propionic acid methyl ester)(1,10-phenanthroline)rhenium(I) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium hexafluorophosphate + (1,10-phenanthroline)Re(CO)3CF3SO3 (247040-04-6) + 3-phenyl-2-[(pyridine-3-carbonyl)amino]propionic acid methyl ester (879123-77-0) → tricarbonyl(3-phenyl-2-[(pyridine-3-carbonyl)amino]propionic acid methyl ester)(1,10-phenanthroline)rhenium(I) hexafluorophosphate (1312104-85-0)

Guidance literature:

In methanol; Re complex and ligand refluxed in MeOH for 3 h; cooled; solvent removed;dissolved in min. amt. of MeOH; satd. soln. of NH4PF6 in MeOH added; H2O added; filtered; ppt. air dried; purified by pptn. from CH2Cl2 with Et2O;

DOI:10.1021/ic200252z

upstream raw materials:

(1,10-phenanthroline)Re(CO)3CF₃SO₃

3-phenyl-2-[(pyridine-3-carbonyl)amino]propionic acid methyl ester