fac-n-Bu₃Sn-Mn(CO)3(PPh₃)2

Base Information

Chemical Name:fac-n-Bu₃Sn-Mn(CO)3(PPh₃)2
CAS No.:321424-51-5
Molecular Formula:C₅₁H₅₇MnO₃P₂Sn
Molecular Weight:953.607
Hs Code.:

fac-n-Bu<sub>3</sub>Sn-Mn(CO)3(PPh<sub>3</sub>)2

Synonyms:

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Chemical Property of fac-n-Bu₃Sn-Mn(CO)3(PPh₃)2

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Technology Process of fac-n-Bu₃Sn-Mn(CO)3(PPh₃)2

There total 2 articles about fac-n-Bu₃Sn-Mn(CO)3(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.5%

: tricarbonyl[4,4-dimethyl-2[tricarbonyl[1',2',3',4',5',6'-η(6)-4'-methyl,2'-[(α-exo-methoxy)(phenyl-κ(2)C(1'')C(2''))methylene-κC(α)]phenyl]chromium],2-oxazoline]manganese(I)

: tricarbonyl[4,4-dimethyl-2[tricarbonyl[1',2',3',4',5',6'-η(6)-4'-methyl,2'-[(α-exo-methoxy)phenylmethylene-κC(α)]phenyl]chromium],2-oxazoline]manganese(I)

: 688-73-3
tri-n-butyl-tin hydride

: 603-35-0
triphenylphosphine

: 321424-51-5
fac-n-Bu₃Sn-Mn(CO)3(PPh₃)2

Guidance literature:: In 1,2-dimethoxyethane; mixt. of Mn-complexes were dissolved at 80 °C in DME under Ar, 2 equiv. of Sn compd. and PPh3 were added, soln. was refluxed for 10 min, allowed to cool to room temp. and stirred overnight; solvent was removed, residue was dissolved in CH2Cl2, silica was added, solvent was removed in vac., residue was dissolved in hexane under Ar, soln. was cooled to 5 °C, eluted with CH2Cl2:hexane (1:9), elem. anal.;
DOI:10.1021/om0006920

Reference yield:

: 114129-80-5
tetra-n-butylammonium tricarbonylbis(triphenylphosphine)manganate

: 688-73-3
tri-n-butyl-tin hydride

: 160024-77-1,17030-38-5,16972-17-1
HMn(CO)3{P(C₆H₅)3}2

: 321424-51-5
Mn(CO)3{P(C₆H₅)3}2((C₄H₉)3Sn)

Guidance literature:: In tetrahydrofuran; byproducts: (C4H9)3SnSn(C4H9)3; Electrochem. Process; electrooxidn. at > -0.94 V vs. SCE under Ar in 0.3 M (C4H9)4NClO4 at 22°C until the passage of current ceases; quantitative formation (IR);
DOI:10.1016/S0022-328X(00)99774-2