Iridium, dicarbonylchloro(4-methylbenzenamine)-

Base Information

• Chemical Name: Iridium, dicarbonylchloro(4-methylbenzenamine)-
• CAS No.: 14243-22-2
• Molecular Formula: C9H9ClIrNO2
• Molecular Weight: 390.849
• Mol file: 14243-22-2.mol

Synonyms:

Chemical Property of Iridium, dicarbonylchloro(4-methylbenzenamine)-

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Iridium, dicarbonylchloro(4-methylbenzenamine)-

There total 1 articles about Iridium, dicarbonylchloro(4-methylbenzenamine)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

Li(1+)*Ir(CO)2Cl2(1-)=Li{Ir(CO)2Cl2} (55095-92-6) + p-toluidine (106-49-0,12221-03-3) → cis-Ir(CO)2Cl(p-NH2C6H4CH3) (59952-74-8,14243-22-2)

Guidance literature:

Inert atmosphere;

DOI:10.1016/j.jorganchem.2019.01.002

Reference yield: 85.0%

ammonium hexafluorophosphate + chlorodicarbonyl(p-toluidine)iridium (14243-22-2,59952-74-8) + mer,cis-(Mn(CO)2(dppm-PP')(dppm-P)Br) (84277-68-9,84232-89-3,224444-98-8,224444-99-9) → (Br(CO)2Mn(μ-dppm)2Ir(CO)2)PF6

Guidance literature:

With CO; In methanol; dichloromethane; soln. (Ir(CO)2Cl(p-toluidine)) in CH2Cl2 added dropwise to a stirred mixt. (Mn(CO)2(dppm)2Br) in CH2Cl2 and NH4PF6 in CH3OH, with Co bubbling into the mixt., and CO bubbling continued for 1 h; mixt. evaporated to dryness, and product extracted into CH2Cl2, and n-hexane added until the soln. became turbid, and the mixt. set aside at -20°C;

DOI:10.1016/S0277-5387(00)81246-2

Reference yield: 82.0%

chlorodicarbonyl(p-toluidine)iridium (14243-22-2,59952-74-8) → Ir2(CO)2Cl2((C6H5)2PCH2CH2CH2P(C6H5)2)2*3CH2Cl2

Guidance literature:

With C₃H₈(P(C₆H₅)2)2; In toluene; addn. of Ir-complex in degassed soln. to phosphine ligand in soln. (pptn.); stirring for 1h; filtration under N2; reducing of volume; addn. of degassed diethyl ether; filtration; washing (diethyl ether); elem. anal.;

upstream raw materials:

Li⁽¹⁺⁾*Ir(CO)2Cl₂^(1-)=Li{Ir(CO)2Cl₂}

p-toluidine

Downstream raw materials:

(η5-cyclopentadienyl)iridium(carbonyl)(triphenylphosphine)

{(η5-C5H5)Rh(μ-CO)(μ-Ph2PPy)Ir(CO)Cl}

Refernces