tetracarbonyl-μ-(1,1',3,3'-tetra-t-butyl-5,5'-pentafulvalene)diiron(Fe-Fe)

Base Information

• Chemical Name: tetracarbonyl-μ-(1,1',3,3'-tetra-t-butyl-5,5'-pentafulvalene)diiron(Fe-Fe)
• CAS No.: 118657-77-5
• Molecular Formula: C₃₀H₄₀Fe₂O₄
• Molecular Weight: 576.339
• Mol file: 118657-77-5.mol

Synonyms:

Chemical Property of tetracarbonyl-μ-(1,1',3,3'-tetra-t-butyl-5,5'-pentafulvalene)diiron(Fe-Fe)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of tetracarbonyl-μ-(1,1',3,3'-tetra-t-butyl-5,5'-pentafulvalene)diiron(Fe-Fe)

There total 1 articles about tetracarbonyl-μ-(1,1',3,3'-tetra-t-butyl-5,5'-pentafulvalene)diiron(Fe-Fe) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

diiodo-tetracarbonyl(1,1',3,3'-tetra-tert-butyl-5,5'-pentafulvalene)diiron + sodium cyclopentadienide → tetracarbonyl-μ-(1,1',3,3'-tetra-t-butyl-5,5'-pentafulvalene)diiron(Fe-Fe) (118657-77-5) + di(cyclopentadienyl)-tetracarbonyl(1,1',3,3'-tetra-tert-butyl-5,5'-pentafulvalene)diiron * 2 toluene

Guidance literature:

In tetrahydrofuran; under Ar: addn. of sodium cyclopentadienyl in THF to a soln. of the diiron compound in THF; stirring for 1 h at roomtemperature; distillation of the solvent in vac.;; dissolving in toluene; centrifugation; concg.; chromatography with Al2O3 (act. III)/toluene; chromatography of the violet to yellow fraction with Al2O3 (act. III)/petroleum ether/toluene; concg. of the yellow fraction in vac. and cooling; elem. anal.;;

DOI:10.1016/0022-328X(91)83287-E