hexacarbonyldi-4-chlorphenyl[η2-di(μ2-thiol)ene]dimanganese(Mn-Mn)

Base Information

• Chemical Name: hexacarbonyldi-4-chlorphenyl[η2-di(μ2-thiol)ene]dimanganese(Mn-Mn)
• CAS No.: 89869-75-0
• Molecular Formula: C₂₀H₈Cl₂Mn₂O₆S₂
• Molecular Weight: 589.194
• Mol file: 89869-75-0.mol

Synonyms:

Chemical Property of hexacarbonyldi-4-chlorphenyl[η2-di(μ2-thiol)ene]dimanganese(Mn-Mn)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of hexacarbonyldi-4-chlorphenyl[η2-di(μ2-thiol)ene]dimanganese(Mn-Mn)

There total 1 articles about hexacarbonyldi-4-chlorphenyl[η2-di(μ2-thiol)ene]dimanganese(Mn-Mn) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

sodium-manganese pentacarbonyl (13859-41-1) + 4-chloro(thiobenzoyl) chloride (3335-27-1) → hexacarbonyldi-4-chlorphenyl[η2-di(μ2-thiol)ene]dimanganese(Mn-Mn) (89869-75-0)

Guidance literature:

In tetrahydrofuran; byproducts: CO, NaCl; dropwise addn. of Na(Mn(CO)5) soln. to thioaroyl chloride soln. under N2, -78°C, within 30 min; fast heating to room temp.; filtration; evapn.; addn. of n-hexane; short stirring; filtration; chromy. (silica gel, n-hexane); recrystn. (minimum amt. of n-hexane); elem. anal.;

DOI:10.1016/0022-328X(83)85161-4

upstream raw materials:

sodium-manganese pentacarbonyl

4-chloro(thiobenzoyl) chloride