Pt(Se₂⁽¹⁵⁾N₂)(P(CH₃)2C₆H₅)2

Base Information

• Chemical Name: Pt(Se₂⁽¹⁵⁾N₂)(P(CH₃)2C₆H₅)2
• CAS No.: 144495-71-6
• Molecular Formula: C₁₆H₂₂N₂P₂PtSe₂
• Molecular Weight: 659.298
• Mol file: 144495-71-6.mol

Synonyms:

Chemical Property of Pt(Se₂⁽¹⁵⁾N₂)(P(CH₃)2C₆H₅)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pt(Se₂⁽¹⁵⁾N₂)(P(CH₃)2C₆H₅)2

There total 2 articles about Pt(Se₂⁽¹⁵⁾N₂)(P(CH₃)2C₆H₅)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[PtCl2(PMe2Ph)2] (15393-14-3,38928-82-4,30759-88-7) + diethyl selenite (14364-97-7) + ammonia (14390-96-6,13767-16-3) → Pt(Se2(15)N2)(P(CH3)2C6H5)2 (144495-71-6)

Guidance literature:

With 1,8-diazabicyclo{5.4.0}undec-7-ene; In dichloromethane; soln. of (EtO)2SeO and Pt complex frozen in liq. N2, apparatus evacuated, soln. warmed to room temp., addn. of (15)NH3, stirred overnight; filtered, evapn., treatment with 1,8-diazabicyclo(5.4.0)undec-7-ene;

DOI:10.1039/DT9920002129

Reference yield:

[PtCl2(PMe2Ph)2] (15393-14-3,38928-82-4,30759-88-7) + tetraselenium-tetranitride (144284-95-7) → Pt(Se2(15)N2)(P(CH3)2C6H5)2 (144495-71-6)

Guidance literature:

In ammonia; High Pressure; heating a mixt. of Se4(15)N4 and Pt-complex in liquid ammonia to 135°C (pressure of 50 atm) for 10 min; cooling at this pressure, evapn. of ammonia, extn. into CH2Cl2, filtn., removal of solvent in vacuo, dissolution of residue in CDCl3, treating with one drop of DBU, monitoring by NMR;

DOI:10.1016/S0277-5387(00)88201-7

upstream raw materials:

[PtCl₂(PMe₂Ph)2]

diethyl selenite

ammonia

tetraselenium-tetranitride