[(pentamethylcyclopentadienyl)Ti(tert-butyl amido)(pyridine)(diphenyl hydrazido^(2-))]

Base Information

• Chemical Name: [(pentamethylcyclopentadienyl)Ti(tert-butyl amido)(pyridine)(diphenyl hydrazido^(2-))]
• CAS No.: 1290629-23-0
• Molecular Formula: C₃₁H₄₀N₄Ti
• Molecular Weight: 516.565
• Mol file: 1290629-23-0.mol

Synonyms:

Chemical Property of [(pentamethylcyclopentadienyl)Ti(tert-butyl amido)(pyridine)(diphenyl hydrazido^(2-))]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [(pentamethylcyclopentadienyl)Ti(tert-butyl amido)(pyridine)(diphenyl hydrazido^(2-))]

There total 1 articles about [(pentamethylcyclopentadienyl)Ti(tert-butyl amido)(pyridine)(diphenyl hydrazido^(2-))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

[(pentamethylcyclopentadienyl)TiCl(pyridine)(diphenyl hydrazido(2-))] (1006654-66-5) + lithium tert-butylamide (37828-54-9) → [(pentamethylcyclopentadienyl)Ti(tert-butyl amido)(pyridine)(diphenyl hydrazido(2-))] (1290629-23-0)

Guidance literature:

In benzene; (Ar or N2); using Schlenk techniques; addn. of soln. of LiNH(t-Bu) in benzene to stirred soln. of (C5Me5)Ti(NNPh2)Cl(py) in benzene, stirring for 4 h at room temp.; removal of volatiles under reduced pressure, extn. into Et2O, filtration, removal of Et2O under reduced pressure, washing with hexanes, drying under reduced pressure; elem. anal.;

DOI:10.1021/om200068k

upstream raw materials:

[(pentamethylcyclopentadienyl)TiCl(pyridine)(diphenyl hydrazido^(2-))]

lithium tert-butylamide