cis-[κ2-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)-κ1-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)ClRh]

Base Information

• Chemical Name: cis-[κ2-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)-κ1-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)ClRh]
• CAS No.: 1238381-14-0
• Molecular Formula: C₄₀H₃₆ClF₂P₂RhS₂
• Molecular Weight: 819.161
• Mol file: 1238381-14-0.mol

Synonyms:

Chemical Property of cis-[κ2-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)-κ1-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)ClRh]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of cis-[κ2-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)-κ1-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)ClRh]

There total 1 articles about cis-[κ2-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)-κ1-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)ClRh] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorobis(cyclooctene)rhodium(I) dimer + diphenyl(2-((4-fluorophenyl)thio)ethyl)phosphane (227174-97-2) → cis-[κ2-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)-κ1-(2-(4-fluorophenylthio)ethyl)diphenylphosphine)ClRh] (1238381-14-0,864228-35-3)

Guidance literature:

In tetrahydrofuran; (N2) soln. ligand in THF was added to soln. Rh complex in THF, stirred at room temp. for 2 h; soln. was evapd. in vacuo, CH2Cl2 was added;

DOI:10.1021/ic101021t

upstream raw materials:

diphenyl(2-((4-fluorophenyl)thio)ethyl)phosphane