Co(C₅H₂(CH₃)(C₆H₅)(CO₂C₂H₅))2⁽¹⁺⁾*PF₆^(1-)=[Co(C₅H₂(CH₃)(C₆H₅)(CO₂C₂H₅))2]PF₆

Base Information

• Chemical Name: Co(C₅H₂(CH₃)(C₆H₅)(CO₂C₂H₅))2⁽¹⁺⁾*PF₆^(1-)=[Co(C₅H₂(CH₃)(C₆H₅)(CO₂C₂H₅))2]PF₆
• CAS No.: 170461-84-4
• Molecular Formula: C₃₀H₃₀CoO₄*F₆P
• Molecular Weight: 658.523
• Mol file: 170461-84-4.mol

Synonyms:

Chemical Property of Co(C₅H₂(CH₃)(C₆H₅)(CO₂C₂H₅))2⁽¹⁺⁾*PF₆^(1-)=[Co(C₅H₂(CH₃)(C₆H₅)(CO₂C₂H₅))2]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Co(C₅H₂(CH₃)(C₆H₅)(CO₂C₂H₅))2⁽¹⁺⁾*PF₆^(1-)=[Co(C₅H₂(CH₃)(C₆H₅)(CO₂C₂H₅))2]PF₆

There total 1 articles about Co(C₅H₂(CH₃)(C₆H₅)(CO₂C₂H₅))2⁽¹⁺⁾*PF₆^(1-)=[Co(C₅H₂(CH₃)(C₆H₅)(CO₂C₂H₅))2]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ammonium hexafluorophosphate + ethyl 2-methyl-4-phenylcyclopenta-1,3-diene-1-carboxylate (128590-29-4) + cobalt(II) chloride (7646-79-9,14543-09-0,16413-89-1) → Co(C5H2(CH3)(C6H5)(CO2C2H5))2(1+)*PF6(1-)=[Co(C5H2(CH3)(C6H5)(CO2C2H5))2]PF6 (170461-84-4,170461-66-2) + Co(C5H2(CH3)(C6H5)(CO2C2H5))2(1+)*PF6(1-)=[Co(C5H2(CH3)(C6H5)(CO2C2H5))2]PF6

Guidance literature:

With NaH; In tetrahydrofuran; inert atmosphere; treatment of ligand with NaH, addn. to CoCl2, stirringand refluxing for 3 h, evapn., dissoln. in 6 M HCl, washing (Et2O), ppt n. on addn. of satd. NH4PF6; recrystn. (MeOH); elem. anal.;

DOI:10.1016/0022-328X(95)05492-8

Reference yield:

ammonium hexafluorophosphate + Co(C5H2(CH3)(C6H5)(CO2C2H5))2(1+)*PF6(1-)=[Co(C5H2(CH3)(C6H5)(CO2C2H5))2]PF6 (170461-84-4,170461-66-2) + (S)-1-phenyl-ethylamine (2627-86-3) → Co(C5H2(CH3)(C6H5)(CONHCH(CH3)C6H5))2(1+)*PF6(1-)=[Co(C5H2(CH3)(C6H5)(CONHCH(CH3)C6H5))2]PF6

Guidance literature:

With H₂O; SOCl₂; In acetonitrile; inert atmosphere; treatment of Co-complex with aq. HCl, evapn., refluxing with SOCl2, evapn. (vac.), stirring with amine (in MeCN) overnight, solvent removal (vac.), dissoln. in MeOH, NH4PF6 addn.; evapn., washing (water), recrystn.; elem. anal.;

DOI:10.1016/0022-328X(95)05492-8

upstream raw materials:

ethyl 2-methyl-4-phenylcyclopenta-1,3-diene-1-carboxylate

cobalt(II) chloride