2-Butanone, 1-(diphenylphosphino)-3,3-dimethyl-, (2Z)-[1-[(diphenylphosphino)methyl]-2,2-dimethylpropylidene]hydrazone , (2Z)-

Base Information

• Chemical Name: 2-Butanone, 1-(diphenylphosphino)-3,3-dimethyl-, (2Z)-[1-[(diphenylphosphino)methyl]-2,2-dimethylpropylidene]hydrazone , (2Z)-
• CAS No.: 143627-09-2
• Molecular Formula: C36H42N2P2
• Molecular Weight: 564.69
• Mol file: 143627-09-2.mol

Synonyms:

Chemical Property of 2-Butanone, 1-(diphenylphosphino)-3,3-dimethyl-, (2Z)-[1-[(diphenylphosphino)methyl]-2,2-dimethylpropylidene]hydrazone , (2Z)-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-Butanone, 1-(diphenylphosphino)-3,3-dimethyl-, (2Z)-[1-[(diphenylphosphino)methyl]-2,2-dimethylpropylidene]hydrazone , (2Z)-

There total 1 articles about 2-Butanone, 1-(diphenylphosphino)-3,3-dimethyl-, (2Z)-[1-[(diphenylphosphino)methyl]-2,2-dimethylpropylidene]hydrazone , (2Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

di(tert-butyl-methyl)ketazine (19838-96-1) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → N,N'-Bis-[1-[(diphenylphosphanyl)-methyl]-2,2-dimethyl-prop-(Z)-ylidene]-hydrazine (143627-09-2)

Guidance literature:

With n-butyllithium; Yield given. Multistep reaction; 1) hexane, THF, -15 deg C, 1h, 2) THF, -78 deg C to RT;

DOI:10.1039/DT9920001469

Reference yield: 89.0%

bis(acetonitrile)dichloroplatinum(II) (13869-38-0,21264-32-4,13869-42-6) + N,N'-Bis-[1-[(diphenylphosphanyl)-methyl]-2,2-dimethyl-prop-(Z)-ylidene]-hydrazine (143627-09-2) → trans-{PtCl2(PPh2CH2C((CH3)3C)=N-N=C((CH3)3C)CH2PPh2)}6

Guidance literature:

In dichloromethane; inert gas; equimolar amounts;; concentration of the solution after 30 min; precipitation by addn. of methanol; elem. anal.;;

DOI:10.1039/DT9930003653

Reference yield: 88.0%

tricarbonyl(cycloheptatriene)molybdenum(0) (121719-12-8,12125-77-8) + N,N'-Bis-[1-[(diphenylphosphanyl)-methyl]-2,2-dimethyl-prop-(Z)-ylidene]-hydrazine (143627-09-2) → {Mo(CO)3((C6H5)2PCH2C(C(CH3)3)NNC(C(CH3)3)CH2P(C6H5)2)}*C6H6

Guidance literature:

With benzene; In benzene; under N2 or Ar, soln. of ligand and Mo complex in benzene kept at 20°C for 16h; evapn. to low volume, addn. of methanol, crystn., elem. anal.;

DOI:10.1039/DT9920001469

upstream raw materials:

di(tert-butyl-methyl)ketazine

chloro-diphenylphosphine

Downstream raw materials:

Z-tert-Butyl diphenylphosphinomethyl ketone hydrazone

N,N'-Bis-[1-(diphenyl-phosphinoylmethyl)-2,2-dimethyl-prop-(Z)-ylidene]-hydrazine

N,N'-Bis-[1-(diphenyl-phosphinothioylmethyl)-2,2-dimethyl-prop-(Z)-ylidene]-hydrazine

[1-(Diphenyl-phosphinothioylmethyl)-2,2-dimethyl-prop-(Z)-ylidene]-hydrazine