Dioctylzinc

Base Information

• Chemical Name: Dioctylzinc
• CAS No.: 14403-26-0
• Molecular Formula: C16H34Zn
• Molecular Weight: 291.836
• DSSTox Substance ID: DTXSID101318269
• Mol file: 14403-26-0.mol

Synonyms:Dioctylzinc;DTXSID101318269;14403-26-0

Chemical Property of Dioctylzinc

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 10
• Exact Mass: 290.195193
• Heavy Atom Count: 17
• Complexity: 79.5

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CCCCCCC[CH2-].CCCCCCC[CH2-].[Zn+2]

Technology Process of Dioctylzinc

There total 1 articles about Dioctylzinc which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

oct-1-ene (111-66-0,25068-25-1) → octane (111-65-9) + dioctylzinc (14403-26-0)

Guidance literature:

With zinc hydride; Zr catalyst; In toluene; at 80 ℃; for 3h; Product distribution; catalyzed hydrozincation of olefins by ZnCl₂;

DOI:10.1007/BF00956175

Reference yield: 96.0%

5-bromopentan-1-nitrile (5414-21-1) + dioctylzinc (14403-26-0) → tridecanenitrile (629-60-7)

Guidance literature:

With 1-methyl-pyrrolidin-2-one; magnesium bromide; nickel dichloride; 2,2-bis(penta-2,4-dienyl)malonic acid dimethyl ester; In tetrahydrofuran; at 25 ℃; for 1h;

DOI:10.1002/anie.200460246

Reference yield: 91.0%

dioctylzinc (14403-26-0) + 3-Methylacetophenone (585-74-0) → 2-(m-tolyl)decan-2-ol

Guidance literature:

With titanium(IV) isopropylate; 1R,2R-[(1S,2R,4R-2-OH-7,7-Me₂-bicycloheptyl)CH₂SO₂NH]2C₆H₁₀; In hexane; toluene; at 20 ℃; for 40h;

DOI:10.1021/jo048683e

upstream raw materials:

oct-1-ene

Downstream raw materials:

6-ketotetradecanoic acid methyl ester

(E)-(9S,12S)-12-(tert-Butyl-diphenyl-silanyloxy)-icos-10-en-9-ol

(R)-1-(4-Methoxy-phenyl)-nonan-1-ol

(S)-1-(4-Methoxy-phenyl)-nonan-1-ol

Refernces