Pt(P(C₆H₅)3)2(H)(Si(C₆H₅)2SiH(C₆H₅)2)

Base Information

• Chemical Name: Pt(P(C₆H₅)3)2(H)(Si(C₆H₅)2SiH(C₆H₅)2)
• CAS No.: 1020269-31-1
• Molecular Formula: C₆₀H₅₂P₂PtSi₂
• Molecular Weight: 1086.27
• Mol file: 1020269-31-1.mol

Synonyms:

Chemical Property of Pt(P(C₆H₅)3)2(H)(Si(C₆H₅)2SiH(C₆H₅)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pt(P(C₆H₅)3)2(H)(Si(C₆H₅)2SiH(C₆H₅)2)

There total 1 articles about Pt(P(C₆H₅)3)2(H)(Si(C₆H₅)2SiH(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethylenebis(triphenylphosphine)platinum(0) (12120-15-9) + 1,1,2,2-tetraphenyldisilane (16343-18-3) → Pt(P(C6H5)3)2(H)(Si(C6H5)2SiH(C6H5)2) (1020269-31-1)

Guidance literature:

In ⁽²⁾H₈-toluene; (inert atm., Schlenk) to an H-shape tube was added a soln. of disilane to the NMR tube side, and a toluene soln. of Pt-complex was added to the other side, disilane-soln. was frozen, a soln. of complex was poured to silane, sealed, shaked, -60°C; not sepd., detected by NMR spectra;

DOI:10.1021/om800012s

Reference yield:

Pt(P(C6H5)3)2(H)(Si(C6H5)2SiH(C6H5)2) (1020269-31-1) → Pt(P(C6H5)3)2(SiH(C6H5)2)2 (1020269-32-2)

Guidance literature:

In ⁽²⁾H₈-toluene; (inert atm., Schlenk) toluene-d7, -60°C- -30°C; not sepd., detected by NMR spectra; Kinetics;

DOI:10.1021/om800012s

Reference yield:

Pt(P(C6H5)3)2(H)(Si(C6H5)2SiH(C6H5)2) (1020269-31-1) → [(triphenylphosphine)Pt(μ-η2-HSiPh2)]2

Guidance literature:

Multi-step reaction with 3 steps

1: ⁽²⁾H₈-toluene

2: ⁽²⁾H₈-toluene

3: ⁽²⁾H₈-toluene

In ⁽²⁾H₈-toluene;

DOI:10.1021/om800012s

upstream raw materials:

ethylenebis(triphenylphosphine)platinum⁽⁰⁾

1,1,2,2-tetraphenyldisilane

Downstream raw materials:

Pt(P(C₆H₅)3)2(SiH(C₆H₅)2)2

Pt(P(C₆H₅)3)2H(SiH(C₆H₅)2)*C₆H₅CH₃

Refernces