trans-[(dimethyl sulfoxide)2Pt(2,4,6-trimethylphenyl)2]

Base Information

• Chemical Name: trans-[(dimethyl sulfoxide)2Pt(2,4,6-trimethylphenyl)2]
• CAS No.: 863499-49-4
• Molecular Formula: C₂₂H₃₄O₂PtS₂
• Molecular Weight: 589.723
• Mol file: 863499-49-4.mol

Synonyms:

Chemical Property of trans-[(dimethyl sulfoxide)2Pt(2,4,6-trimethylphenyl)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-[(dimethyl sulfoxide)2Pt(2,4,6-trimethylphenyl)2]

There total 1 articles about trans-[(dimethyl sulfoxide)2Pt(2,4,6-trimethylphenyl)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichlorobis(dimethylsulfoxide)platinum(II) (30729-25-0,25794-47-2,15274-33-6,22840-91-1,75992-73-3,14568-13-9) + SnMe3(C6H2Me3-2,4,6) (1077-62-9) → trans-[(dimethyl sulfoxide)2Pt(2,4,6-trimethylphenyl)2] (863499-49-4,79058-35-8)

Guidance literature:

In dimethyl sulfoxide; byproducts: (CH3)3SnCl; under Ar; soln. of tin compd. in DMSO added to Pt complex, mixt. stirredat 90-100°C for 8 h; evapn., residue washed with pentane, dried under vac., recrystn. from CH2Cl2;

DOI:10.1021/om050076+

Reference yield: 28.0%

trans-[(dimethyl sulfoxide)2Pt(2,4,6-trimethylphenyl)2] (863499-49-4,79058-35-8) + 3,6-di(thiophen-2-yl)-1,2,4,5-tetrazine (59918-60-4) → Pt2(μ-3,6-bis(thienyl)-1,2,4,5-tetrazine(-2H))(dimethylsulfoxide)2(2,4,6-trimethylphenyl)2] (1029698-81-4)

Guidance literature:

In toluene; refluxing mixt. of platinum compd., tetrazine deriv. and toluene for 5 d; evapn., recrystn. (CH2Cl2/heptane), elem. anal.;

DOI:10.1016/j.jorganchem.2007.10.045

upstream raw materials:

dichlorobis(dimethylsulfoxide)platinum(II)

SnMe₃(C₆H₂Me₃-2,4,6)

Downstream raw materials:

Pt2(μ-3,6-bis(thienyl)-1,2,4,5-tetrazine(-2H))(dimethylsulfoxide)2(2,4,6-trimethylphenyl)2]