9-chloro-11-cyano-10-ethoxy-8-hydroxy-3a,11b-dihydro-1-thiacyclopentaphenanthrene

Base Information

• Chemical Name: 9-chloro-11-cyano-10-ethoxy-8-hydroxy-3a,11b-dihydro-1-thiacyclopentaphenanthrene
• CAS No.: 108234-06-6
• Molecular Formula: C₁₉H₁₄ClNO₂S
• Molecular Weight: 355.845
• Mol file: 108234-06-6.mol

Synonyms:

Chemical Property of 9-chloro-11-cyano-10-ethoxy-8-hydroxy-3a,11b-dihydro-1-thiacyclopentaphenanthrene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-chloro-11-cyano-10-ethoxy-8-hydroxy-3a,11b-dihydro-1-thiacyclopentaphenanthrene

There total 1 articles about 9-chloro-11-cyano-10-ethoxy-8-hydroxy-3a,11b-dihydro-1-thiacyclopentaphenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 22.0%

thiophene (188290-36-0,8014-23-1,25233-34-5) + 3-Azido-6-chloro-5-ethoxy-4-(phenylethynyl)-3,5-cyclohexadiene-1,2-dione (99947-83-8) → 5-Chloro-4-ethoxy-6-hydroxy-2-thiophen-3-yl-biphenyl-3-carbonitrile (108234-05-5) + 2-chloro-4-cyano-3-ethoxy-6-phenyl-5-(thiacyclopenta-2,4-dien-2-yl)phenol (108234-04-4) + 9-chloro-11-cyano-10-ethoxy-8-hydroxy-3a,11b-dihydro-1-thiacyclopentaphenanthrene (108234-06-6) + 6-chloro-4-cyano-5-ethoxy-7-hydroxy-3a,11b-dihydro-1-thiacyclopentaphenanthrene (108234-07-7)

Guidance literature:

for 6h; Title compound not separated from byproducts; Heating;

DOI:10.1021/jo00388a034

upstream raw materials:

thiophene

3-Azido-6-chloro-5-ethoxy-4-(phenylethynyl)-3,5-cyclohexadiene-1,2-dione