MnBr₂(CNt-Bu)(PPhMe₂)

Base Information

• Chemical Name: MnBr₂(CNt-Bu)(PPhMe₂)
• CAS No.: 117344-21-5
• Molecular Formula: C₁₃H₂₀Br₂MnNP
• Molecular Weight: 436.028
• Mol file: 117344-21-5.mol

Synonyms:

Chemical Property of MnBr₂(CNt-Bu)(PPhMe₂)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of MnBr₂(CNt-Bu)(PPhMe₂)

There total 2 articles about MnBr₂(CNt-Bu)(PPhMe₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

MnBr2(P(CH3)2(C6H5))2 + tert-butylisonitrile (119072-55-8,7188-38-7) → MnBr2(CNt-Bu)(PPhMe2) (117344-21-5)

Guidance literature:

In toluene; stirring for 48 h under Ar-atmosphere; filtered, washed with toluene, dried in vacuo at 40°C, elem. anal.;

DOI:10.1039/DT9880002261

Reference yield:

manganese(II) bromide (13446-03-2) + tert-butylisonitrile (119072-55-8,7188-38-7) + Dimethyl(phenyl)phosphine (672-66-2) → MnBr2(CNt-Bu)(PPhMe2) (117344-21-5)

Guidance literature:

In toluene; PPhMe2, then CNt-Bu was added to MnBr2 in toluene, mixture was stirred for 48 h under Ar-atmosphere; filtered, washed with toluene, dried in vacuo at 40°C, elem. anal.;

DOI:10.1039/DT9880002261

Reference yield:

MnBr2(CNt-Bu)(PPhMe2) (117344-21-5) → {trans-bis(dimethylphenylphosphine)tetrakis(t-butyl isocyanide)manganese(II)}{MnBr4}

Guidance literature:

In ethanol; Mn-complex dissolved in EtOH under argon; pptn. with toluene, filtered off, elem. anal.;

DOI:10.1039/DT9880002261

upstream raw materials:

manganese(II) bromide

tert-butylisonitrile

Dimethyl(phenyl)phosphine