2-Ethenyl-2-methyl-4,4,6,6-tetraphenyl-1,3,5,2,4,6-trioxatrisilinane

Base Information

• Chemical Name: 2-Ethenyl-2-methyl-4,4,6,6-tetraphenyl-1,3,5,2,4,6-trioxatrisilinane
• CAS No.: 1457-02-9
• Molecular Formula: C27H26O3Si3
• Molecular Weight: 482.75000
• DSSTox Substance ID: DTXSID30506909
• Nikkaji Number: J2.804.490I
• Wikidata: Q82362878
• Mol file: 1457-02-9.mol

Synonyms:1457-02-9;2-Ethenyl-2-methyl-4,4,6,6-tetraphenyl-1,3,5,2,4,6-trioxatrisilinane;SCHEMBL8383296;DTXSID30506909;1-methyl-1-vinyl-3,3,5,5-tetraphenylcyclotrisiloxane

Chemical Property of 2-Ethenyl-2-methyl-4,4,6,6-tetraphenyl-1,3,5,2,4,6-trioxatrisilinane

Chemical Property:

• PSA: 27.69000
• LogP: 3.36020
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 5
• Exact Mass: 482.11897429
• Heavy Atom Count: 33
• Complexity: 563

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si]1(O[Si](O[Si](O1)(C2=CC=CC=C2)C3=CC=CC=C3)(C4=CC=CC=C4)C5=CC=CC=C5)C=C

Technology Process of 2-Ethenyl-2-methyl-4,4,6,6-tetraphenyl-1,3,5,2,4,6-trioxatrisilinane

There total 2 articles about 2-Ethenyl-2-methyl-4,4,6,6-tetraphenyl-1,3,5,2,4,6-trioxatrisilinane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.5%

Dichloromethylvinylsilane (124-70-9) + 1,1,3,3-tetraphenyldisiloxane-1,3-diol (1104-93-4) → 2-Methyl-4,4,6,6-tetraphenyl-2-vinyl-[1,3,5,2,4,6]trioxatrisilinane (1457-02-9) + 1,7-dichloro-1,7-dimethyl-1,7-divinyl-3,3,5,5-tetraphenyltetrasiloxane (109305-36-4)

Guidance literature:

With pyridine; In toluene; for 3h; Heating;

Reference yield: 22.8%

Dichloromethylvinylsilane (124-70-9) + 1,1,3,3-tetraphenyldisiloxane-1,3-diol (1104-93-4) → 2-Methyl-4,4,6,6-tetraphenyl-2-vinyl-[1,3,5,2,4,6]trioxatrisilinane (1457-02-9) + 2,8-Dimethyl-4,4,6,6,10,10,12,12-octaphenyl-2,8-divinyl-1,3,5,7,9,11-hexaoxa-2,4,6,8,10,12-hexasila-cyclododecane (79902-86-6)

Guidance literature:

With pyridine; In toluene; for 3h; Heating;

Reference yield:

1,1,1,3,3-pentamethyl-1,3-disiloxane (1438-82-0) + 2-Methyl-4,4,6,6-tetraphenyl-2-vinyl-[1,3,5,2,4,6]trioxatrisilinane (1457-02-9) → 2-Methyl-2-[2-(1,1,3,3,3-pentamethyl-disiloxanyl)-ethyl]-4,4,6,6-tetraphenyl-[1,3,5,2,4,6]trioxatrisilinane (58110-16-0)

Guidance literature:

dihydrogen hexachloroplatinate;

upstream raw materials:

Dichloromethylvinylsilane

1,1,3,3-tetraphenyldisiloxane-1,3-diol

Downstream raw materials:

2-Methyl-2-[2-(1,1,3,3,3-pentamethyl-disiloxanyl)-ethyl]-4,4,6,6-tetraphenyl-[1,3,5,2,4,6]trioxatrisilinane

C₃₄H₄₈O₅Si₆