Lithium, (4-methoxyphenyl)-

Base Information

• Chemical Name: Lithium, (4-methoxyphenyl)-
• CAS No.: 14774-77-7
• Molecular Formula: C7H7LiO
• Molecular Weight: 114.073
• DSSTox Substance ID: DTXSID60472709
• Mol file: 14774-77-7.mol

Synonyms:4-methoxyphenyllithium;p-methoxyphenyllithium;Lithium, (4-methoxyphenyl)-;14774-77-7;SCHEMBL734298;DTXSID60472709;VVGYSTVTNKJNGF-UHFFFAOYSA-N

Chemical Property of Lithium, (4-methoxyphenyl)-

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 114.06569328
• Heavy Atom Count: 9
• Complexity: 140

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [Li+].COC1=CC=[C-]C=C1

Technology Process of Lithium, (4-methoxyphenyl)-

There total 7 articles about Lithium, (4-methoxyphenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

1-bromo-4-methoxy-benzene (104-92-7) → p-methoxyphenyllithium (14774-77-7)

Guidance literature:

With n-butyllithium; In hexane; pentane; at 20 ℃;

DOI:10.1021/acs.organomet.8b00783

Reference yield:

para-iodoanisole (696-62-8) + phenyllithium (591-51-5) → iodobenzene (591-50-4) + p-methoxyphenyllithium (14774-77-7)

Guidance literature:

In tetrahydrofuran; biphenyl; pentane; at -50.16 ℃; Equilibrium constant; Inert atmosphere;

DOI:10.1021/jo8020083

Reference yield:

n-butyllithium (109-72-8,29786-93-4) + 1-bromo-4-methoxy-benzene (104-92-7) → p-methoxyphenyllithium (14774-77-7)

Guidance literature:

DOI:10.1016/S0040-4039(01)81980-8

upstream raw materials:

1-bromo-4-methoxy-benzene

n-butyllithium

1-fluoro-4-methoxybenzene

para-iodoanisole

Downstream raw materials:

4-(2-pyridinyl)anisole

1-(4-methoxy-phenyl)-isoquinoline; picrate

4-(4-methoxy-phenyl)-1,2,5-trimethyl-piperidin-4-ol

(2-(4-methoxyphenyl)-8-methylquinoline)

Refernces

Benzopentalenonaphthalenones from the intramolecular capture of a merocyanine derived from a naphthopyran

10.1039/c0cc02986f

The study presents the synthesis and characterization of novel, highly colored benzopentalenonaphthalenones derived from the intramolecular capture of a merocyanine moiety from diarylmethanol-substituted 2H-naphtho[1,2-b]pyrans under acidic conditions. These compounds exhibit interesting photochromic properties, changing color upon irradiation with ultraviolet light and reverting to colorless upon cessation of irradiation. The researchers also observed that the coloration was influenced by the electronic and steric properties of the substituents. Further, they explored the cascade process that leads to the formation of these compounds, involving initial intramolecular trapping of a cation and subsequent cyclization, tautomerization, and oxidation steps. The study provides insights into the design of new functional dyes with potential applications in areas such as dye-sensitized solar cells, photodynamic therapy, and sensor systems.