1,4:5,8-Dimethanonaphthalen-9-ol, 1,4,4a,5,6,7,8,8a-octahydro-, stereo isomer

Base Information

• Chemical Name: 1,4:5,8-Dimethanonaphthalen-9-ol, 1,4,4a,5,6,7,8,8a-octahydro-, stereo isomer
• CAS No.: 28068-45-3
• Molecular Formula: C₁₂H₁₆O
• Molecular Weight: 176.258
• Mol file: 28068-45-3.mol

Synonyms:1,4:5,8-Dimethanonaphthalen-9-ol,1,4,4a,5,6,7,8,8a-octahydro- (6CI); 1,4:5,8-Dimethanonaphthalen-9-ol,1,4,4a,5,6,7,8,8a-octahydro-, anti-endo,exo- (8CI)

Chemical Property of 1,4:5,8-Dimethanonaphthalen-9-ol, 1,4,4a,5,6,7,8,8a-octahydro-, stereo isomer

Chemical Property:

• Vapor Pressure: 0.000314mmHg at 25°C
• Boiling Point: 285.7°Cat760mmHg
• Flash Point: 106.8°C
• PSA: 20.23000
• Density: 1.205g/cm³
• LogP: 1.82540

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,4:5,8-Dimethanonaphthalen-9-ol, 1,4,4a,5,6,7,8,8a-octahydro-, stereo isomer

There total 4 articles about 1,4:5,8-Dimethanonaphthalen-9-ol, 1,4,4a,5,6,7,8,8a-octahydro-, stereo isomer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C14H12Cl6O2 → endo,exo-tetracyclo<6.2.1.13,6.02,7>dodec-4-en-anti-11-ol (28068-45-3)

Guidance literature:

With ethanol; sodium; Heating;

DOI:10.1021/jo00394a054

Reference yield:

C12H10Cl6O → endo,exo-tetracyclo<6.2.1.13,6.02,7>dodec-4-en-anti-11-ol (28068-45-3)

Guidance literature:

With sodium; tert-butyl alcohol;

DOI:10.1021/ja00762a009

Reference yield:

ant-7-norbornenol (694-70-2) → endo,exo-tetracyclo<6.2.1.13,6.02,7>dodec-4-en-anti-11-ol (28068-45-3)

Guidance literature:

Multi-step reaction with 2 steps

1: 150 °C

2: Na, tBuOH

With sodium; tert-butyl alcohol;

DOI:10.1021/ja00762a009

upstream raw materials:

ant-7-norbornenol

hexachlorocyclopentadiene

Downstream raw materials:

endo,exo-Tetracyclo<6.2.1.1^3,6.0^2,7>dodecan-11-syn-ol

anti-11-benzyloxy-endo,exo-tetracyclo<6.2.1.1^3,6.0^2,7>dodec-4-ene

anti-11-benzyloxy-exo-4-fluoro-endo,exo-tetracyclo<6.2.1.1^3,6.0^2,7>dodecane

anti-11-benzyloxy-exo-4-fluoro-exo,exo-tetracyclo<6.2.1.1^3,6.0^2,7>dodecane