9-[(4-Methylphenyl)methyl]anthracene

Base Information

• Chemical Name: 9-[(4-Methylphenyl)methyl]anthracene
• CAS No.: 1498-79-9
• Molecular Formula: C22H18
• Molecular Weight: 282.385
• DSSTox Substance ID: DTXSID30507355
• Wikidata: Q82363535
• Mol file: 1498-79-9.mol

Synonyms:9-[(4-METHYLPHENYL)METHYL]ANTHRACENE;1498-79-9;DTXSID30507355

Chemical Property of 9-[(4-Methylphenyl)methyl]anthracene

Chemical Property:

• XLogP3: 7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 282.140850574
• Heavy Atom Count: 22
• Complexity: 329

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)CC2=C3C=CC=CC3=CC4=CC=CC=C42

Technology Process of 9-[(4-Methylphenyl)methyl]anthracene

There total 17 articles about 9-[(4-Methylphenyl)methyl]anthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(9-anthryl)-p-methylbenzyl chloride (77032-89-4) → 9-(p-methylbenzyl)anthracene (1498-79-9)

Guidance literature:

With sodium tetrahydroborate; trifluoroacetic acid; In dichloromethane; at 0 ℃; for 0.166667h;

DOI:10.1021/ja00395a025

Reference yield: 81.0%

9-chloroanthracene (716-53-0) + 4-Methylbenzyl chloride (104-82-5) → 9-(p-methylbenzyl)anthracene (1498-79-9)

Guidance literature:

With Ni(IBiox-6)[P(OEt)₃]Br₂; magnesium; In tetrahydrofuran; at 50 ℃; for 4h; Schlenk technique; Glovebox;

DOI:10.1021/acs.organomet.0c00515

Reference yield: 78.0%

Anthracen-9-yl-p-tolyl-methanol (77032-85-0) → 9-(p-methylbenzyl)anthracene (1498-79-9)

Guidance literature:

With sodium tetrahydroborate; trifluoroacetic acid; In dichloromethane; at 0 ℃; for 0.166667h;

DOI:10.1021/ja00395a025

upstream raw materials:

anthracen-9(10H)-one

4-tolylmagnesium chloride

(9,10-Dihydro-anthracen-9-yl)-p-tolyl-methanol

Anthracen-9-yl-p-tolyl-methanol

Downstream raw materials:

9-(4-methylbenzyl)-1,4-dihydroxytriptycene

5,11-bis-(4-methyl-benzyl)-5,6,11,12-tetrahydro-5,12;6,11-di-o-benzeno-dibenzo[a,e]cyclooctene