(NE)-N-[(2,3,4-trimethoxyphenyl)methylidene]hydroxylamine

Base Information

Chemical Name:(NE)-N-[(2,3,4-trimethoxyphenyl)methylidene]hydroxylamine
CAS No.:15258-55-6
Molecular Formula:C10H13 N O4
Molecular Weight:211.218
Hs Code.:
European Community (EC) Number:239-298-4
Mol file:15258-55-6.mol

Synonyms:2,3,4-Trimethoxybenzaldehyde oxime;15258-55-6;AKOS008939531

Suppliers and Price of (NE)-N-[(2,3,4-trimethoxyphenyl)methylidene]hydroxylamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Labseeker
2,3,4-TRIMETHOXYBENZALDEHYDEOXIME 95
10g
$ 1925.00

American Custom Chemicals Corporation
2,3,4-TRIMETHOXYBENZALDEHYDE OXIME 95.00%
5MG
$ 496.76

Total 4 raw suppliers

Chemical Property of (NE)-N-[(2,3,4-trimethoxyphenyl)methylidene]hydroxylamine

Chemical Property:

Vapor Pressure:0.000123mmHg at 25°C
Boiling Point:321.5°Cat760mmHg
Flash Point:148.2°C
PSA：60.28000
Density:1.14g/cm³
LogP:1.52050
XLogP3:1.6
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:5
Rotatable Bond Count:4
Exact Mass:211.08445790
Heavy Atom Count:15
Complexity:210

Purity/Quality:

98%Min ^*data from raw suppliers

2,3,4-TRIMETHOXYBENZALDEHYDEOXIME 95 ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC1=C(C(=C(C=C1)C=NO)OC)OC
Isomeric SMILES:COC1=C(C(=C(C=C1)/C=N/O)OC)OC

Technology Process of (NE)-N-[(2,3,4-trimethoxyphenyl)methylidene]hydroxylamine

There total 3 articles about (NE)-N-[(2,3,4-trimethoxyphenyl)methylidene]hydroxylamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 2103-57-3
2,3,4-trimethoxybenzaldehyde

: 15258-55-6
2,3,4‐trimethoxybenzaldoxime

Guidance literature:: With pyridine; hydroxylamine hydrochloride; In ethanol; at 20 ℃;
DOI:10.1021/acs.oprd.8b00113

Reference yield:

: C₁₂H₁₈NO₃⁽¹⁺⁾*CF₃O₃S^(1-)

: 15258-55-6
2,3,4‐trimethoxybenzaldoxime

Guidance literature:: With hydroxylamine hydrochloride; potassium carbonate; In water; 1,2-dichloro-ethane; acetonitrile; at 20 ℃; for 19h;
DOI:10.1016/j.tet.2020.131255

Reference yield:

: 634-36-6
1,2,3-trimethoxybenzene

: 15258-55-6
2,3,4‐trimethoxybenzaldoxime

Guidance literature:: Multi-step reaction with 2 steps

1: 1,2-dichloro-ethane / 4 h / 100 °C / Inert atmosphere

2: hydroxylamine hydrochloride; potassium carbonate / 1,2-dichloro-ethane; acetonitrile; water / 19 h / 20 °C

With hydroxylamine hydrochloride; potassium carbonate; In water; 1,2-dichloro-ethane; acetonitrile; 1: |Vilsmeier-Haack Formylation;
DOI:10.1016/j.tet.2020.131255