1-(3-Nitrophenyl)ethanone oxime

Base Information

Chemical Name:1-(3-Nitrophenyl)ethanone oxime
CAS No.:7471-32-1
Molecular Formula:C8H8 N2 O3
Molecular Weight:180.163
Hs Code.:
NSC Number:403578
DSSTox Substance ID:DTXSID90419682
Nikkaji Number:J1.136.385G

Synonyms:NSC403578;7471-32-1;3'-Nitroacetophenoneoxime;DTXSID90419682;AKOS006243084;NSC-403578;1-(3-NITROPHENYL)ETHANONE OXIME

Suppliers and Price of 1-(3-Nitrophenyl)ethanone oxime

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 6 raw suppliers

Chemical Property of 1-(3-Nitrophenyl)ethanone oxime

Chemical Property:

Vapor Pressure:0mmHg at 25°C
Boiling Point:334.546°C at 760 mmHg
Flash Point:156.128°C
Density:1.293g/cm³
XLogP3:1.7
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:1
Exact Mass:180.05349212
Heavy Atom Count:13
Complexity:222

Purity/Quality:: 98%+ ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(=NO)C1=CC(=CC=C1)[N+](=O)[O-]
Isomeric SMILES:C/C(=N/O)/C1=CC(=CC=C1)[N+](=O)[O-]

Technology Process of 1-(3-Nitrophenyl)ethanone oxime

There total 5 articles about 1-(3-Nitrophenyl)ethanone oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.4%

: 121-89-1
3-Nitroacetophenone

: 7471-32-1
m-nitroacetophenone oxime

Guidance literature:: With hydroxylamine hydrochloride; sodium acetate; In methanol; water; at 25 ℃; for 2h;

Reference yield: 41.0%

: 586-39-0,51209-60-0
1-nitro-3-vinyl-benzene

: 7471-32-1
m-nitroacetophenone oxime

Guidance literature:: With nitric oxide; tetraethylammonium borohydride; (pyridine)Co(dimethylglyoxime)2Cl; In 1,2-dimethoxyethane; isopropyl alcohol; for 30h; Ambient temperature;
DOI:10.1021/jo00232a005

Reference yield:

: 99-61-6
3-nitro-benzaldehyde

: 7471-32-1
m-nitroacetophenone oxime

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) n-BuLi / 1.) THF, hexane, RT, 1.5 h, 2.) a) RT, 1 h, b) 65 deg C, 5 h

2: 33 percent / EtONO, Et₄NBH₄, ClCoIII(DH)2py / benzene / 25 h / Ambient temperature

With n-butyllithium; ethyl nitrite; tetraethylammonium borohydride; In benzene;
DOI:10.1021/jo00256a001