chloroplatinum(1+) (2-{(E)-[(2-formylphenyl)imino]methyl}phenyl)azanide

Base Information

• Chemical Name: chloroplatinum(1+) (2-{(E)-[(2-formylphenyl)imino]methyl}phenyl)azanide
• CAS No.: 73920-56-6
• Molecular Formula: C14H11 Cl N2 O Pt
• Molecular Weight: 453.7869
• Mol file: 73920-56-6.mol

Synonyms:Benzaldehyde,2-[[(2-aminophenyl)methylene]amino]-, platinum complex; NSC 357162

Chemical Property of chloroplatinum(1+) (2-{(E)-[(2-formylphenyl)imino]methyl}phenyl)azanide

Chemical Property:

• Vapor Pressure: 1.47E-08mmHg at 25°C
• Boiling Point: 457.6°C at 760 mmHg
• Flash Point: 230.5°C

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of chloroplatinum(1+) (2-{(E)-[(2-formylphenyl)imino]methyl}phenyl)azanide

There total 2 articles about chloroplatinum(1+) (2-{(E)-[(2-formylphenyl)imino]methyl}phenyl)azanide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

potassium tetrachloroplatinate + o-aminobenzaldehyde (529-23-7) → cis-[N-(o-aminobenzylidene)anthranilaldehydato-O,N,N']chloroplatinum (73920-56-6)

Guidance literature:

With HCl; N₂; In water; to hot deaerated soln. of K2PtCl4 in H2O added dropwise soln. of the organic compound in H2O with few drops of HCl, N2 bubbled through soln., stirred and heated for 3 h, cooled; filtered, dissolved in CHCl3, filtered, slow evapd., elem. anal.;

DOI:10.1021/ja00534a026

Reference yield: 16.0%

potassium tetrachloroplatinate + [(C6H4)2(C8H7N2)2](2+)*2BF4(1-) = [(C6H4)2(C8H7N2)2](BF4)2 → cis-[N-(o-aminobenzylidene)anthranilaldehydato-O,N,N']chloroplatinum (73920-56-6)

Guidance literature:

In water; the organic compound added to soln. of K2PtCl4 in water, mixture stirred at 35-40°C for 5 days; mixture filtered, residue collected in a filter, extracted from residueby stirring in the absence of heat in CHCl3 (8 h), mixture filtered, filtrate evapd., crystals washed several times with CHCl3;

DOI:10.1021/ja00534a026

Reference yield:

Pt(N-(o-aminobenzylidene)anthranilaldehyde)Cl (73920-56-6) → ClPt[P(C6H5)3][OCHC6H4NCHC6H4NH]

Guidance literature:

With PPh₃; In acetonitrile; soln. of the Pt-complex was treated with PPh3 in the dark; elem. anal.;

DOI:10.1021/ja00547a024

upstream raw materials:

o-aminobenzaldehyde

Downstream raw materials:

Pt(AAA)(tol)Cl

Pt(AAA)(mba)Cl

[Pt(CO₂C₆H₄NCHC₆H₄P(C₆H₅)2)Cl]