Benzo[b]thiophene-3-carboxylic acid, 4,5,6,7-tetrahydro-2-[[(methylthio)thioxomethyl]amino]-, ethyl ester

Base Information

Chemical Name:Benzo[b]thiophene-3-carboxylic acid, 4,5,6,7-tetrahydro-2-[[(methylthio)thioxomethyl]amino]-, ethyl ester
CAS No.:155686-60-5
Molecular Formula:C₁₃H₁₇NO₂S₃
Molecular Weight:315.481
Hs Code.:
Mol file:155686-60-5.mol

Synonyms:methyl N-[3-carbethoxy-(5,6,7,8-tetrahydrobenzo)thienyl]dithiocarbamate;2-Methylsulfanylthiocarbonylamino-4,5,6,7-tetrahydro-benzo[b]thiophene-3-carboxylic acid ethyl ester;2-methylsulfanylthiocarbonylamino-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylic acid ethyl ester;methyl N-(3-carbethoxy-4,5,6,7-tetrahydrobenzo[b]thienyl)dithiocarbamate;

Suppliers and Price of Benzo[b]thiophene-3-carboxylic acid, 4,5,6,7-tetrahydro-2-[[(methylthio)thioxomethyl]amino]-, ethyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
Ethyl2-(((methylthio)carbonothioyl)amino)-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate 97%
10g
$ 424.00

Crysdot
Ethyl2-(((methylthio)carbonothioyl)amino)-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate 97%
5g
$ 306.00

Total 2 raw suppliers

Chemical Property of Benzo[b]thiophene-3-carboxylic acid, 4,5,6,7-tetrahydro-2-[[(methylthio)thioxomethyl]amino]-, ethyl ester

Chemical Property:

PSA：123.96000
LogP:3.93640

Purity/Quality:

99% ^*data from raw suppliers

Ethyl2-(((methylthio)carbonothioyl)amino)-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Benzo[b]thiophene-3-carboxylic acid, 4,5,6,7-tetrahydro-2-[[(methylthio)thioxomethyl]amino]-, ethyl ester

There total 3 articles about Benzo[b]thiophene-3-carboxylic acid, 4,5,6,7-tetrahydro-2-[[(methylthio)thioxomethyl]amino]-, ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.6%

: 75-15-0,12122-00-8
carbon disulfide

: 4506-71-2
ethyl 2-amino-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate

: 77-78-1
dimethyl sulfate

: 155686-60-5
2-methylsulfanylthiocarbonylamino-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylic acid ethyl ester

Guidance literature:: carbon disulfide; ethyl 2-amino-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate; With sodium hydroxide; In dimethyl sulfoxide; at 20 ℃; for 0.5h;

dimethyl sulfate; In dimethyl sulfoxide; for 3h;

Reference yield:

: 4506-71-2
ethyl 2-amino-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylate

: 155686-60-5
2-methylsulfanylthiocarbonylamino-4,5,6,7-tetrahydrobenzo[b]thiophene-3-carboxylic acid ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: aq. NaOH / dimethylsulfoxide / 0.5 h / 20 °C

2: dimethylsulfoxide / 2 h / 5 - 10 °C

With sodium hydroxide; In dimethyl sulfoxide;
DOI:10.1002/ardp.200700017