Oxirane, triphenyl-, (3S)-

Base Information

Chemical Name:Oxirane, triphenyl-, (3S)-
CAS No.:157556-88-2
Molecular Formula:C20H16O
Molecular Weight:272.346
Hs Code.:
DSSTox Substance ID:DTXSID90455924
Nikkaji Number:J885.313D
Wikidata:Q82278095
Mol file:157556-88-2.mol

Synonyms:Oxirane, triphenyl-, (3S)-;157556-88-2;2,2,3alpha-Triphenyloxirane;DTXSID90455924

Suppliers and Price of Oxirane, triphenyl-, (3S)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 0 raw suppliers

Chemical Property of Oxirane, triphenyl-, (3S)-

Chemical Property:

PSA：12.53000
LogP:4.70170
XLogP3:4.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:272.120115130
Heavy Atom Count:21
Complexity:314

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C1=CC=C(C=C1)C2C(O2)(C3=CC=CC=C3)C4=CC=CC=C4
Isomeric SMILES:C1=CC=C(C=C1)[C@H]2C(O2)(C3=CC=CC=C3)C4=CC=CC=C4

Technology Process of Oxirane, triphenyl-, (3S)-

There total 9 articles about Oxirane, triphenyl-, (3S)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 58-72-0
Triphenylethylene

: 157556-88-2
(S)-2,2,3-triphenyloxirane

Guidance literature:: With 4-methylmorpholine N-oxide; 3-chloro-benzenecarboperoxoic acid; (salen)Mn(III); In dichloromethane; at -78 ℃;
DOI:10.1016/00404-0399(50)1088Y-

Reference yield: 75.0%

: 1029690-06-9
(3S)-2,2-diphenyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane

: 157556-88-2
(S)-2,2,3-triphenyloxirane

: 183849-26-5
(R)-2,2,3-triphenyloxirane

Guidance literature:: (3S)-2,2-diphenyl-3-[(S)-2-(p-toluenesulfinyl)phenyl]oxirane; With tert.-butyl lithium; In tetrahydrofuran; at -78 ℃; for 0.25h; Inert atmosphere;

With water; ammonium chloride; In tetrahydrofuran; optical yield given as %ee; Inert atmosphere;
DOI:10.1021/ol8005387

Reference yield:

: 58-72-0
Triphenylethylene

: 157556-88-2
(S)-2,2,3-triphenyloxirane

: 183849-26-5
(R)-2,2,3-triphenyloxirane

Guidance literature:: With Oxone; C₆H₁₀O₆(C₃H₄)2; tetra(n-butyl)ammonium hydrogensulfate; edetate disodium; sodium hydrogencarbonate; In water; acetonitrile; at 0 ℃; for 2h; Product distribution; other reaction time, solvent, reagent;
DOI:10.1021/ja972272g