TRIS(3-FLUOROPHENYL)PHOSPHINE

Base Information

• Chemical Name: TRIS(3-FLUOROPHENYL)PHOSPHINE
• CAS No.: 23039-94-3
• Molecular Formula: C18H12F3P
• Molecular Weight: 316.262
• Hs Code.: 2903999090
• Mol file: 23039-94-3.mol

Synonyms:Tris(3-fluorophenyl)phosphine 98%;

Chemical Property of TRIS(3-FLUOROPHENYL)PHOSPHINE

Chemical Property:

• Vapor Pressure: 2.26E-05mmHg at 25°C
• Melting Point: 62 °C
• Boiling Point: 371.1 °C at 760 mmHg
• Flash Point: 178.2 °C
• PSA: 13.59000
• LogP: 3.86210
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: Air Sensitive

Purity/Quality:

98%, ^*data from raw suppliers

Tris(3-fluorophenyl)phosphine 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of TRIS(3-FLUOROPHENYL)PHOSPHINE

There total 2 articles about TRIS(3-FLUOROPHENYL)PHOSPHINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

3-fluorobromobenzene (1073-06-9) → tris(3-fluorophenyl)phosphine (23039-94-3)

Guidance literature:

3-fluorobromobenzene; With magnesium; In diethyl ether; for 2h; Inert atmosphere; Reflux;

With phosphorus trichloride; In diethyl ether; for 1h; Reflux; Inert atmosphere;

DOI:10.1002/chem.201200480

Reference yield:

→ tris(3-fluorophenyl)phosphine (23039-94-3)

Guidance literature:

3-Fluor-phenylmagnesiumbromid m. PCl3;

Reference yield: 95.0%

rhodium(III) trichloride hydrate + tris(3-fluorophenyl)phosphine (23039-94-3) → tris(tris(3-fluorophenyl)phosphine)rhodium(I) chloride

Guidance literature:

In ethanol; water; at 78 ℃; for 2.5h; Inert atmosphere;

DOI:10.1021/ol502661g

upstream raw materials:

3-fluorobromobenzene

Downstream raw materials:

(CO)3NiP(C₆H₄F-m)3

cis-dichlorobis{tris(3-fluorophenyl)phosphane}platinum(II)

[(acetyl)(tris(m-fluorophenyl)phosphine)Co(CO)3]

[(P(C₆H₄F)3)2PdCl(C₆H₂(CHNCH₂C₆H₅)2C(CH₃)3)]

Refernces

• 1、 Brune, Hans Albert,Falck, Manfred,Hemmer, Reinhard,Schmidtberg, Guenter,Alt, Helmut G.. "Syntheses and Spectroscopic Investigations of Substituted cis- and trans-Dichlorobis(triphenylphospane)platinum(II) Compounds". . p. 2791 - 2802. Retrieved 2007/10/02.