Gibberellin A67

Base Information

Chemical Name:Gibberellin A67
CAS No.:105593-16-6
Molecular Formula:C₁₉H₂₄O₆
Molecular Weight:348.396
Hs Code.:
DSSTox Substance ID:DTXSID401317115
Nikkaji Number:J147.246A
Mol file:105593-16-6.mol

Synonyms:Gibberellin A67;GA67;CHEBI:142005;DTXSID401317115;ent-10beta,13,15alpha-trihydroxy-20-norgibberell-16-ene-7,19-dioic acid 19,10-lactone;(1R,4aR,4bR,7S,9S,9aR,10S,10aR)-7,9-dihydroxy-1-methyl-8-methylene-13-oxododecahydro-4a,1-(epoxymethano)-7,9a-methanobenzo[a]azulene-10-carboxylic acid;(1R,4aR,4bR,7S,9S,9aR,10S,10aR)-7,9-dihydroxy-1-methyl-8-methylidene-13-oxododecahydro-4a,1-(epoxymethano)-7,9a-methanobenzo[a]azulene-10-carboxylic acid;7alpha,9beta-dihydroxy-1beta-methyl-8-methylidene-13-oxo-4a,1alpha-epoxymethano-4aalpha,4bbeta-gibbane-10beta-carboxylic acid

Suppliers and Price of Gibberellin A67

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 1 raw suppliers

Chemical Property of Gibberellin A67

Chemical Property:

Boiling Point:624.3±55.0 °C(Predicted)
PKA:4.05±0.70(Predicted)
PSA：104.06000
Density:1.45±0.1 g/cm3(Predicted)
LogP:1.25110
XLogP3:0.1
Hydrogen Bond Donor Count:3
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:1
Exact Mass:348.15728848
Heavy Atom Count:25
Complexity:731

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC12CCCC3(C1C(C45C3CCC(C4)(C(=C)C5O)O)C(=O)O)OC2=O
Isomeric SMILES:C[C@@]12CCC[C@@]3([C@@H]1[C@@H]([C@]45[C@H]3CC[C@](C4)(C(=C)[C@H]5O)O)C(=O)O)OC2=O

Technology Process of Gibberellin A67

There total 6 articles about Gibberellin A67 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 105593-10-0
ent-13-acetoxy-10β-hydroxy-15-oxo-20-norgibberell-16-ene-7,19-dioic acid 7-methyl ester 19,10-lactone

: 105593-16-6
ent-10β,13,15α-trihydroxy-20-norgibberell-16-ene-7,19-dioic acid 19,10-lactone

Guidance literature:: Multi-step reaction with 2 steps

1: 20 mg / Zn, HOAc / 1 h / Ambient temperature

2: 15 mg / aq. K₂CO₃ (1 mol/l) / methanol / 60 h / Ambient temperature

With potassium carbonate; acetic acid; zinc; In methanol;

Reference yield:

: 75885-03-9
gibberellin A₂₀ methyl ester 13-acetate

: 105593-16-6
ent-10β,13,15α-trihydroxy-20-norgibberell-16-ene-7,19-dioic acid 19,10-lactone

Guidance literature:: Multi-step reaction with 4 steps

1: 270 mg / SeO₂, tert-butyl hydroperoxide / CH₂Cl₂; H₂O / 24 h / Ambient temperature

2: 1.) oxalyl chloride, DMSO, 2.) i-Pr₂NEt / 1.) CH₂Cl₂, -78 deg C, 1 h, 2.) -78 deg C to r. t., 1 h

3: 20 mg / Zn, HOAc / 1 h / Ambient temperature

4: 15 mg / aq. K₂CO₃ (1 mol/l) / methanol / 60 h / Ambient temperature

With tert.-butylhydroperoxide; selenium(IV) oxide; oxalyl dichloride; potassium carbonate; acetic acid; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; zinc; In methanol; dichloromethane; water;

Reference yield:

: 105593-05-3
ent-13-acetoxy-10β,15β-dihydroxy-20-norgibberell-16-ene-7,19-dioic acid 7-methyl ester 19,10-lactone

: 105593-16-6
ent-10β,13,15α-trihydroxy-20-norgibberell-16-ene-7,19-dioic acid 19,10-lactone

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) oxalyl chloride, DMSO, 2.) i-Pr₂NEt / 1.) CH₂Cl₂, -78 deg C, 1 h, 2.) -78 deg C to r. t., 1 h

2: 20 mg / Zn, HOAc / 1 h / Ambient temperature

3: 15 mg / aq. K₂CO₃ (1 mol/l) / methanol / 60 h / Ambient temperature

With oxalyl dichloride; potassium carbonate; acetic acid; dimethyl sulfoxide; N-ethyl-N,N-diisopropylamine; zinc; In methanol;