(Z)-4-bromomethylene-ε-caprolactone

Base Information

• Chemical Name: (Z)-4-bromomethylene-ε-caprolactone
• CAS No.: 1422253-47-1
• Molecular Formula: C₇H₉BrO₂
• Molecular Weight: 205.051
• Mol file: 1422253-47-1.mol

Synonyms:

Chemical Property of (Z)-4-bromomethylene-ε-caprolactone

Chemical Property:

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Useful:

Technology Process of (Z)-4-bromomethylene-ε-caprolactone

There total 1 articles about (Z)-4-bromomethylene-ε-caprolactone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-(bromomethylidene)cyclohexanone (1407169-65-6) → (E)-4-bromomethylene-ε-caprolactone (1422253-46-0) + (Z)-4-bromomethylene-ε-caprolactone (1422253-47-1) + 4-(bromomethylene)cyclohexanol (1411975-95-5)

Guidance literature:

With cyclohexanone monooxygenase Phe₄₃₂Ile/Thr₄₃₃Gly/Leu₁₄₃Met/Phe₅₀₅Cys; for 12h; diastereoselective reaction; Enzymatic reaction;

DOI:10.1002/adsc.201200759

upstream raw materials:

4-(bromomethylidene)cyclohexanone