2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Base Information

Chemical Name:2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS No.:159087-40-8
Molecular Formula:C12H21BO2
Molecular Weight:208.109
Hs Code.:2934999090
European Community (EC) Number:804-790-5
DSSTox Substance ID:DTXSID30450892
Nikkaji Number:J618.790K
Wikidata:Q82270727
Mol file:159087-40-8.mol

Synonyms:2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;159087-40-8;2-hex-1-ynyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;Hex-1-yn-1-ylboronic acid pinacol ester;2-(Hex-1-ynyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane;SCHEMBL14800542;DTXSID30450892;MFCD25948958;AKOS025392240;AS-1006;F12160;2-(1-Hexynyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Suppliers and Price of 2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

SynQuest Laboratories
2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1 g
$ 312.00

SynQuest Laboratories
2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
500 mg
$ 244.00

Matrix Scientific
2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >90%
1g
$ 322.00

Matrix Scientific
2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane >90%
500mg
$ 261.00

Crysdot
2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 95+%
5g
$ 675.00

Alichem
2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
5g
$ 722.25

AK Scientific
2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
1g
$ 484.00

Total 3 raw suppliers

Chemical Property of 2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Chemical Property:

PSA：18.46000
LogP:2.81140
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:3
Exact Mass:208.1634601
Heavy Atom Count:15
Complexity:267

Purity/Quality:

More than 95% ^*data from raw suppliers

2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:B1(OC(C(O1)(C)C)(C)C)C#CCCCC

Technology Process of 2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

There total 3 articles about 2-(Hex-1-yn-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 693-02-7
hex-1-yne

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 159087-40-8
2-hex-1-ynyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:: With Cu⁽¹⁺⁾*CF₃O₃S^(1-)*C₂₂H₃₅N; triethylamine; In benzene; at 20 ℃; for 12h;
DOI:10.1039/c6sc02668k

Reference yield: 94.0%

: 61676-62-8
2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

: 693-02-7
hex-1-yne

: 159087-40-8
2-hex-1-ynyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:: hex-1-yne; With n-butyllithium; In diethyl ether; hexane; at -78 ℃; for 1h; Inert atmosphere;

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane; In diethyl ether; hexane; at -78 ℃; for 2h; Inert atmosphere;

With hydrogenchloride; In diethyl ether; hexane; water;
DOI:10.1002/anie.201103601

Reference yield: 85.0%

: 76-09-5
2,3-dimethyl-2,3-butane diol

: 1086138-68-2
C₁₀H₇BO₃

: 693-02-7
hex-1-yne

: 159087-40-8
2-hex-1-ynyl-4,4,5,5-tetramethyl-[1,3,2]dioxaborolane

Guidance literature:: C₁₀H₇BO₃; hex-1-yne; With 2-Mercapto-1-methylimidazole; In toluene; at 110 ℃; for 18h;

2,3-dimethyl-2,3-butane diol; at 20 ℃; for 1h;
DOI:10.1021/acscatal.0c02682