Triphenyl(prop-2-enyl)phosphanium

Base Information

• Chemical Name: Triphenyl(prop-2-enyl)phosphanium
• CAS No.: 15912-76-2
• Molecular Formula: C21H20P
• Molecular Weight: 0.00000
• DSSTox Substance ID: DTXSID301297792
• Nikkaji Number: J82.462C
• ChEMBL ID: CHEMBL3306408
• Mol file: 15912-76-2.mol

Synonyms:triphenyl(prop-2-enyl)phosphanium;Allyltriphenylphosphonium;15912-76-2;Triphenyl(2-propenyl)phosphonium;Phosphonium, triphenyl-2-propenyl-;NSC126440;allyl triphenyl phosphine;allyl(triphenyl)phosphonium;NCIOpen2_007936;SCHEMBL837677;CHEMBL3306408;FLNRHACWTVIBQS-UHFFFAOYSA-;DTXSID301297792;Triphenyl-2-propen-1-ylphosphonium;triphenyl-prop-2-enylphosphanium chloride

Chemical Property of Triphenyl(prop-2-enyl)phosphanium

Chemical Property:

• PSA: 0.00000
• LogP: 0.00000
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 303.130262636
• Heavy Atom Count: 22
• Complexity: 284

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C=CC[P+](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3

Technology Process of Triphenyl(prop-2-enyl)phosphanium

There total 1 articles about Triphenyl(prop-2-enyl)phosphanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ allyltriphenylphosphonium (15912-76-2)

Guidance literature:

Triphenylphosphin, Allylbromid;

Reference yield: 87.0%

(1R,2S,3R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3-(1-tosyl-1H-indol-3-yl)cyclopropane-1-carbaldehyde + allyltriphenylphosphonium (15912-76-2) → 3-((1S,2R,3R)-2-((E)-buta-1,3-dien-1-yl)-3-(((tert-butyldiphenylsilyl)oxy)methyl)cyclopropyl)-1-tosyl-1H-indole

Guidance literature:

allyltriphenylphosphonium; With n-butyllithium; In tetrahydrofuran; at -78 - 0 ℃; for 1h; Inert atmosphere;

(1R,2S,3R)-2-(((tert-butyldiphenylsilyl)oxy)methyl)-3-(1-tosyl-1H-indol-3-yl)cyclopropane-1-carbaldehyde; In tetrahydrofuran; at -78 - 20 ℃; for 4h; Inert atmosphere;

DOI:10.1021/acs.orglett.9b02687

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