Benzenesulfonimidoyl chloride, N-methyl-

Base Information

• Chemical Name: Benzenesulfonimidoyl chloride, N-methyl-
• CAS No.: 15934-21-1
• Molecular Formula: C7H8ClNOS
• Molecular Weight: 189.66300
• Mol file: 15934-21-1.mol

Synonyms:N-Methylbenzolsulfonimidoylchlorid;N-methyl-S-phenylsulfonimidoyl chloride;N-methyl-benzenesulfonimidoyl chloride;(S-chloro-N-methylsulfonimidoyl)benzene;Benzenesulfonimidoyl chloride,N-methyl;

Chemical Property of Benzenesulfonimidoyl chloride, N-methyl-

Chemical Property:

• PSA: 37.81000
• LogP: 3.16280

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Benzenesulfonimidoyl chloride, N-methyl-

There total 3 articles about Benzenesulfonimidoyl chloride, N-methyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

N-methyl-S-phenylsulfinamide (69726-27-8) → N-methyl-S-phenylsulfonimidoyl chloride (15934-21-1)

Guidance literature:

With chlorine;

DOI:10.1021/jo01327a001

Reference yield:

sodium benzenesulfonate (873-55-2) → N-methyl-S-phenylsulfonimidoyl chloride (15934-21-1)

Guidance literature:

Multi-step reaction with 2 steps

1.1: oxalyl dichloride / dichloromethane; N,N-dimethyl-formamide / 1 h / 20 °C

1.2: 20 °C

2.1: tert-butylhypochlorite / acetonitrile / 1 h / 20 °C

With oxalyl dichloride; tert-butylhypochlorite; In dichloromethane; N,N-dimethyl-formamide; acetonitrile;

DOI:10.1039/c7ob02028g

Reference yield:

→ N-methyl-S-phenylsulfonimidoyl chloride (15934-21-1)

Guidance literature:

N-Methylbenzolsulfinamid 1a, t-BuOCl;

DOI:10.1021/jo01327a051

upstream raw materials:

N-methyl-S-phenylsulfinamide

sodium benzenesulfonate

Downstream raw materials:

(+/-)-2-(N-methylphenylsulfonimidoyl)-1-phenylethanone

2-(N-Methylphenylsulfonimidoyl)cyclohexanone

S-(4-Methoxyphenyl)-N-methyl-S-phenylsulfoximine

S-butyl-N-methyl-S-phenylsulfoximine

Refernces