Silane, (3-ethenyl-1-methyl-3-cyclohexen-1-yl)dimethylphenyl-

Base Information

Chemical Name:Silane, (3-ethenyl-1-methyl-3-cyclohexen-1-yl)dimethylphenyl-
CAS No.:159692-35-0
Molecular Formula:C17H24Si
Molecular Weight:256.463
Hs Code.:
DSSTox Substance ID:DTXSID90452695
Nikkaji Number:J1.987.979H
Mol file:159692-35-0.mol

Synonyms:159692-35-0;Silane, (3-ethenyl-1-methyl-3-cyclohexen-1-yl)dimethylphenyl-;DTXSID90452695;2-Ethenyl-4-methyl-4-(dimethylphenylsilyl)cyclohexene

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Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Silane, (3-ethenyl-1-methyl-3-cyclohexen-1-yl)dimethylphenyl-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:3
Exact Mass:256.164727300
Heavy Atom Count:18
Complexity:334

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(CCC=C(C1)C=C)[Si](C)(C)C2=CC=CC=C2

Technology Process of Silane, (3-ethenyl-1-methyl-3-cyclohexen-1-yl)dimethylphenyl-

There total 8 articles about Silane, (3-ethenyl-1-methyl-3-cyclohexen-1-yl)dimethylphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 7486-35-3
tri-n-butyl(vinyl)tin

: 245657-53-8
Trifluoro-methanesulfonic acid 5-(dimethyl-phenyl-silanyl)-5-methyl-cyclohex-1-enyl ester

: 159692-35-0
(+/-)-5-(dimethylphenylsilanyl)-5-methyl-1-vinyl-1-cyclohexene

Guidance literature:: With lithium chloride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In N,N-dimethyl-formamide; at 70 ℃; for 1h;
DOI:10.1039/CC9960000225

Reference yield: 58.0%

: (+/-)-(E/Z)-2-<3-(dimethylphenylsilanyl)-3-methylcyclohexylidene>-1-(trimethylsiloxy)ethane

: 159692-35-0
(+/-)-5-(dimethylphenylsilanyl)-5-methyl-1-vinyl-1-cyclohexene

: (+/-)-(E/Z)-2-<3-(dimethylphenylsilanyl)-3-methylcyclohexylidene>ethanol

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; hexane; at 35 ℃; for 4h;

Reference yield:

: 67263-00-7
3-(dimethyl(phenyl)silyl)-3-methylcyclohexanone

: 159692-35-0
(+/-)-5-(dimethylphenylsilanyl)-5-methyl-1-vinyl-1-cyclohexene

Guidance literature:: Multi-step reaction with 2 steps

1.1: LDA / tetrahydrofuran / 0.5 h / -78 °C

1.2: 94 percent / tetrahydrofuran / -78 - 0 °C

2.1: 93 percent / LiCl / Pd(PPh₃)4 / dimethylformamide / 1 h / 70 °C

With lithium chloride; lithium diisopropyl amide; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; N,N-dimethyl-formamide; 1.1: Metallation / 1.2: Substitution / 2.1: Substitution;
DOI:10.1021/jo990648y