Benzene, 1-[(2,2-dimethyl-6-methylenecyclohexyl)methyl]-4-methoxy-

Base Information

Chemical Name:Benzene, 1-[(2,2-dimethyl-6-methylenecyclohexyl)methyl]-4-methoxy-
CAS No.:160058-93-5
Molecular Formula:C17H24O
Molecular Weight:244.377
Hs Code.:
DSSTox Substance ID:DTXSID90455121

Synonyms:Benzene, 1-[(2,2-dimethyl-6-methylenecyclohexyl)methyl]-4-methoxy-;160058-93-5;DTXSID90455121

Suppliers and Price of Benzene, 1-[(2,2-dimethyl-6-methylenecyclohexyl)methyl]-4-methoxy-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Benzene, 1-[(2,2-dimethyl-6-methylenecyclohexyl)methyl]-4-methoxy-

Chemical Property:

XLogP3:5
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:244.182715385
Heavy Atom Count:18
Complexity:284

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(CCCC(=C)C1CC2=CC=C(C=C2)OC)C

Technology Process of Benzene, 1-[(2,2-dimethyl-6-methylenecyclohexyl)methyl]-4-methoxy-

There total 9 articles about Benzene, 1-[(2,2-dimethyl-6-methylenecyclohexyl)methyl]-4-methoxy- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 2065-66-9
methyl-triphenylphosphonium iodide

: 160058-92-4
2-(p-methoxybenzyl)-3,3-dimethylcyclohexanone

: 160058-93-5
2-(p-methoxybenzyl)-3,3-dimethyl-1-methylenecyclohexane

Guidance literature:: With sodium tert-pentoxide; In toluene; at 60 - 65 ℃; for 3h;
DOI:10.1016/S0040-4039(00)78225-6

Reference yield: 77.0%

: thiocarbonic acid O-[3-(4-methoxy-benzyl)-2,2-dimethyl-4-methylene-cyclohexyl] ester O-pentafluorophenyl ester

: 160058-93-5
2-(p-methoxybenzyl)-3,3-dimethyl-1-methylenecyclohexane

Guidance literature:: With 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; In benzene; for 1h; Heating;
DOI:10.1002/ejoc.200600389

Reference yield:

: 866474-73-9
3-[(E)-5-(4-Methoxy-phenyl)-3-methyl-pent-3-enyl]-2,2-dimethyl-oxirane

: 160058-93-5
2-(p-methoxybenzyl)-3,3-dimethyl-1-methylenecyclohexane

Guidance literature:: Multi-step reaction with 3 steps

1: 60 percent / Mn; 2,4,6-collidine; Me₃SiCl / Cp₂TiCl₂ / tetrahydrofuran / 20 °C

2: 76 percent / DMAP / CH₂Cl₂ / 2 h / 20 °C

3: 77 percent / AIBN; HSnBu₃ / benzene / 1 h / Heating

With 2,4,6-trimethyl-pyridine; dmap; manganese; chloro-trimethyl-silane; 2,2'-azobis(isobutyronitrile); tri-n-butyl-tin hydride; bis(cyclopentadienyl)titanium dichloride; In tetrahydrofuran; dichloromethane; benzene; 3: Barton-McCombie deoxygenation;
DOI:10.1002/ejoc.200600389