Cyclopropanecarboxylic acid, 2-benzoyl-, (1R,2R)-rel-

Base Information

• Chemical Name: Cyclopropanecarboxylic acid, 2-benzoyl-, (1R,2R)-rel-
• CAS No.: 1601-82-7
• Molecular Formula: C11H10O3
• Molecular Weight: 190.199
• Mol file: 1601-82-7.mol

Synonyms:(+/-)-cis-2-Benzoyl-cyclopropan-carbonsaeure-(1);cis-2-Benzoyl-1-carboxy-cyclopropan;1-Benzoyl-cyclopropan-2-carbonsaeure;cis-2-Benzoyl-cyclopropan-1-carbonsaeure;Cyclopropanecarboxylic acid, 2-benzoyl-, trans-;

Chemical Property of Cyclopropanecarboxylic acid, 2-benzoyl-, (1R,2R)-rel-

Chemical Property:

• PSA: 54.37000
• LogP: 1.59000

Purity/Quality:

97% ^*data from raw suppliers

trans-2-Benzoyl-cyclopropanecarboxylicAcid ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Cyclopropanecarboxylic acid, 2-benzoyl-, (1R,2R)-rel-

There total 17 articles about Cyclopropanecarboxylic acid, 2-benzoyl-, (1R,2R)-rel- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

3-oxabicyclo[3.1.0]hexane-2,4-dione (5617-74-3) + benzene (71-43-2,26181-88-4,54682-86-9,13967-78-7,174973-66-1) → cis 2-benzoylcyclopropanecarboxylic acid (1601-81-6,1601-82-7,22811-70-7)

Guidance literature:

With aluminum (III) chloride; Sealed tube; Inert atmosphere;

DOI:10.1021/jacs.6b01728

Reference yield:

2-benzoyl-cyclopropane-1,1-dicarboxylic acid (6366-29-6) → (+/-)-trans-2-benzoyl-cyclopropane-carboxylic acid-(1) (1601-82-7)

Guidance literature:

at 180 ℃;

DOI:10.1021/ja01334a056

Reference yield:

2-benzoyl-cyclopropane-1,1-dicarboxylic acid (6366-29-6) → cis 2-benzoylcyclopropanecarboxylic acid (1601-81-6,1601-82-7,22811-70-7)

Guidance literature:

at 180 ℃;

DOI:10.1021/ja01334a056

upstream raw materials:

2-benzoyl-cyclopropane-1,1-dicarboxylic acid

3-oxabicyclo[3.1.0]hexane-2,4-dione

benzene

cis-1,2-cyclopropanedicarboxylic acid anhydride

Downstream raw materials:

3-(2-morpholin-4-yl-ethyl)-5-phenyl-3,4-diaza-bicyclo[4.1.0]hept-4-en-2-one

5-oxo-5-phenylvaleric acid

trans-1-Benzoyl-2-brom-cyclopropan

cis-1-Benzoyl-2-brom-cyclopropan

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