1-Chloro-1,2,3,4,5-pentaphenyl-1H-silole

Base Information

• Chemical Name: 1-Chloro-1,2,3,4,5-pentaphenyl-1H-silole
• CAS No.: 16030-07-2
• Molecular Formula: C34H25ClSi
• Molecular Weight: 497.111
• DSSTox Substance ID: DTXSID10508103
• Nikkaji Number: J1.894.262C
• Mol file: 16030-07-2.mol

Synonyms:16030-07-2;1-Chloro-1,2,3,4,5-pentaphenyl-1H-silole;DTXSID10508103

Chemical Property of 1-Chloro-1,2,3,4,5-pentaphenyl-1H-silole

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 5
• Exact Mass: 496.1414050
• Heavy Atom Count: 36
• Complexity: 737

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C([Si](C(=C2C3=CC=CC=C3)C4=CC=CC=C4)(C5=CC=CC=C5)Cl)C6=CC=CC=C6

Technology Process of 1-Chloro-1,2,3,4,5-pentaphenyl-1H-silole

There total 6 articles about 1-Chloro-1,2,3,4,5-pentaphenyl-1H-silole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Phenyltrichlorosilane (98-13-5) + diphenyl acetylene (501-65-5) → 1-chloro-1,2,3,4,5-pentaphenyl-1-silacyclopentadiene (16030-07-2)

Guidance literature:

Multistep reaction; (i) Li, (ii) THF, /BRN= 508730/;

DOI:10.1021/ja01050a013

Reference yield:

Phenyltrichlorosilane (98-13-5) + 1,4-dilithio-1,2,3,4-tetraphenylbutadiene (21289-08-7,99643-57-9) → 1-chloro-1,2,3,4,5-pentaphenyl-1-silacyclopentadiene (16030-07-2)

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 7.5h; Reflux;

Reference yield:

diphenyl acetylene (501-65-5) → 1-chloro-1,2,3,4,5-pentaphenyl-1-silacyclopentadiene (16030-07-2)

Guidance literature:

Multi-step reaction with 2 steps

1: 90 percent / Li / tetrahydrofuran / 20 °C

2: tetrahydrofuran / Heating

With lithium; In tetrahydrofuran;

DOI:10.1021/ma0213504

upstream raw materials:

Phenyltrichlorosilane

diphenyl acetylene

(E,E)-(1,2,3,4-tetramethyl-1,3-butadien-1,4-ylidene)-dilithium

1,4-dilithio-1,2,3,4-tetraphenylbutadiene

Downstream raw materials:

1,2,3,4,5,1',2',3',4',5'-decaphenyl-1H,1'H-1,1'-oxy-bis-silole

1,1'-bis(1,2,3,4,5-pentaphenyl-1-silacyclopentadien)

1,2,3,4,5-pentaphenylsilacyclopentadiene

11-[(1,2,3,4,5-pentaphenylsilolyl)oxy]-1-undecyne