3-(AMINOCARBONYL)-1-BENZYLPYRIDINIUM

Base Information

• Chemical Name: 3-(AMINOCARBONYL)-1-BENZYLPYRIDINIUM
• CAS No.: 16183-83-8
• Molecular Formula: C13H13N2O
• Molecular Weight: 213.259
• Mol file: 16183-83-8.mol

Synonyms:1-benzylnicotinamidium cation;1-benzyl-3-carbamoylpyridinium ion;1-benzyl-3-carbamoyl-pyridinium;

Chemical Property of 3-(AMINOCARBONYL)-1-BENZYLPYRIDINIUM

Chemical Property:

• PSA: 47.96000
• LogP: 2.00550

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-(AMINOCARBONYL)-1-BENZYLPYRIDINIUM

There total 95 articles about 3-(AMINOCARBONYL)-1-BENZYLPYRIDINIUM which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1-Benzyl-1,4-dihydronicotinamide (952-92-1) → 1-benzyl-3-carbamoylpyridinium ion (16183-83-8)

Guidance literature:

With 1,1,1,3,3,3-hexachloro-propan-2-one; In dichloromethane; at 25 ℃; Kinetics; Mechanism; var. of solvent;

DOI:10.1039/c39810000444

Reference yield: 85.0%

1-Benzyl-1,4-dihydronicotinamide (952-92-1) → 1-benzyl-3-carbamoylpyridinium ion (16183-83-8) + 2,4,6-trimethylaniline (88-05-1)

Guidance literature:

In acetonitrile; at 25 ℃; Kinetics;

DOI:10.1002/chem.201902405

Reference yield:

1-Benzyl-1,4-dihydronicotinamide (952-92-1) + 2,2,2-Trifluoroacetophenone (434-45-7) → 1-phenyl-2,2,2-trifluoromethylethanol (340-04-5,340-05-6) + 1-benzyl-3-carbamoylpyridinium ion (16183-83-8)

Guidance literature:

With NaHCO₃ - Na₂CO₃ buffer; In water; isopropyl alcohol; at 50 ℃; Mechanism; Rate constant; deuterium isotope effect;

DOI:10.1021/ja00529a060

upstream raw materials:

Δ¹-pyrroline-2-carboxylic acid

1-Benzyl-1,4-dihydronicotinamide

1,4-Butanedithiol

10-dodecyl-3-methylisoalloxazine

Downstream raw materials:

10-methylacridinium cation

1-Benzyl-1,4-dihydronicotinamide

C₂₃H₂₁N₂O₂⁽¹⁺⁾

1-Benzyl-6-methyl-1,6-dihydro-pyridine-3-carboxylic acid amide

Refernces

• 1、 Hilvert, Donald,Kaiser, E. T.. "New Semisynthetic Flavoenzymes Based on a Tetrameric Protein Template, Glyceraldehyde-3-phosphate Dehydrogenase". . p. 5805 - 5806. Retrieved 1985.
• 2、 Peterson, Ryan L.,Himes, Richard A.,Kotani, Hiroaki,Suenobu, Tomoyoshi,Tian, Li,Siegler, Maxime A.,Solomon, Edward I.,Fukuzumi, Shunichi,Karlin, Kenneth D.. "Cupric superoxo-mediated intermolecular C-H activation chemistry". . p. 1702 - 1705. Retrieved 2011.
• 3、 Devi, Tarali,Lee, Yong-Min,Jung, Jieun,Sankaralingam, Muniyandi,Nam, Wonwoo,Fukuzumi, Shunichi. "A Chromium(III)-Superoxo Complex as a Three-Electron Oxidant with a Large Tunneling Effect in Multi-Electron Oxidation of NADH Analogues". . p. 3510 - 3515. Retrieved 2017.
• 4、 Zhu,Zhao,Cheng. "Mechanisms of the oxidations of NAD(P)H model Hantzsch 1,4-dihydropyridines by nitric oxide and its donor N-methyl-N-nitrosotoluene-p-sulfonamide". . p. 8158 - 8163. Retrieved 2000.
• 5、 Fukuzumi, Shunichi,Suenobu, Tomoyoshi,Patz, Matthias,Hirasaka, Takeomi,Itoh, Shinobu,Fujitsuka, Mamoru,Ito, Osamu. "Selective one-electron and two-electron reduction of C60 with NADH and NAD dimer analogues via photoinduced electron transfer". . p. 8060 - 8068. Retrieved 1998.
• 6、 Ellis, William W,Raebiger, James W,Curtis, Calvin J,Bruno, Joseph W,DuBois, Daniel L. "Hydricities of BzNADH, CH5Mo(PMe3)(CO)2H, and C5Me5Mo(PMe3)(CO)2H in acetonitrile.". . p. 2738 - 2743. Retrieved 2004.
• 7、 Yamashita, Kohichi,Kajiwara, Shuta,Ohkubo, Katsutoshi. "Methylviologen-Accelerated Photoreduction of Tris(acetylacetonato)cobalt(III) with 1-Benzyl-1,4-dihydronicotinamide". . p. 73 - 78. Retrieved 1989.
• 8、 Fukuzumi, Shunichi,Nishizawa, Nobuaki,Tanaka, Toshio. "EFFECTS OF MAGNESIUM(II) ION ON HYDRIDE-TRANSFER REACTIONS FROM AN NADH MODEL COMPOUND TO p-BENZOQUINONE DERIVATIVES. THE QUANTITATIVE EVALUATION BASED ON THE REACTION MECHANISM". . p. 371 - 378. Retrieved 1985.
• 9、 Hübner, Olaf,Himmel, Hans-J?rg,Kaifer, Elisabeth,Walter, Petra,Wild, Ute. "Evaluation of the Synthetic Scope and the Reaction Pathways of Proton-Coupled Electron Transfer with Redox-Active Guanidines in C?H Activation Processes". supporting information. p. 16504 - 16513. Retrieved 2020/12/01.
• 10、 Ilic, Stefan,Pandey Kadel, Usha,Basdogan, Yasemin,Keith, John A.,Glusac, Ksenija D.. "Thermodynamic Hydricities of Biomimetic Organic Hydride Donors". supporting information. p. 4569 - 4579. Retrieved 2018/04/10.