6-Oxomyristic acid

Base Information

• Chemical Name: 6-Oxomyristic acid
• CAS No.: 1619-89-2
• Molecular Formula: C14H26O3
• Molecular Weight: 242.35400
• Hs Code.: 2918300090
• Mol file: 1619-89-2.mol

Synonyms:6-Oxo-tetradecansaeure;Tetradecanoic acid,6-oxo;6-ketotetradecanoic acid;6-Oxomyristic acid;CO6;6-oxo-tetradecanoic acid;6-Ketotetradecansaeure;6CO Myristic acid;Ketobutolsaeure;

Chemical Property of 6-Oxomyristic acid

Chemical Property:

• Melting Point: 72.5 °C
• Boiling Point: 391.3±25.0 °C(Predicted)
• PKA: 4.69±0.10(Predicted)
• PSA: 54.37000
• Density: 0.964±0.06 g/cm3(Predicted)
• LogP: 3.95110

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 6-Oxomyristic acid

There total 15 articles about 6-Oxomyristic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1,6-tetradecanediol (28047-87-2) → 6-Oxo-tetradecansaeure (1619-89-2)

Guidance literature:

With Jones reagent; In acetone; at 0 - 20 ℃; for 0.5h;

DOI:10.1021/jo500791y

Reference yield:

Nonanoyl chloride (764-85-2) → 6-Oxo-tetradecansaeure (1619-89-2)

Guidance literature:

Multi-step reaction with 2 steps

1: Et₃N / CHCl₃

2: aq. K₂CO₃

With potassium carbonate; triethylamine; In chloroform;

DOI:10.1039/jr9630005768

Reference yield:

1-bromo-octane (111-83-1) → 6-Oxo-tetradecansaeure (1619-89-2)

Guidance literature:

Multi-step reaction with 3 steps

1.1: magnesium; iodine / diethyl ether / 1 h / 0 - 20 °C / Inert atmosphere

1.2: 1.5 h / 0 - 20 °C / Inert atmosphere

2.1: toluene-4-sulfonic acid / methanol / 3 h / 20 °C

3.1: Jones reagent / acetone / 0.5 h / 0 - 20 °C

With Jones reagent; iodine; toluene-4-sulfonic acid; magnesium; In methanol; diethyl ether; acetone;

DOI:10.1021/jo500791y

upstream raw materials:

1-octylcyclohex-1-ene

octylcyclohexyl alcohol

ethylmagnesium bromide

2-ethoxycarbonyl-1-cyclopentanone

Refernces

• 1、 Christie,W.W. et al.. "-". . p. 5768 - 5771. Retrieved 1963.