1,3-benzodioxol-5-yl 4-methylbenzenesulfonate

Base Information

Chemical Name:1,3-benzodioxol-5-yl 4-methylbenzenesulfonate
CAS No.:16387-85-2
Molecular Formula:C14H12O5S
Molecular Weight:292.312
Hs Code.:
Mol file:16387-85-2.mol

Synonyms:5-(Toluol-4-sulfonyloxy)-benzo[1,3]dioxol;3,4-methylenedioxyphenyl tosylate;5-(toluene-4-sulfonyloxy)-benzo[1,3]dioxole;

Suppliers and Price of 1,3-benzodioxol-5-yl 4-methylbenzenesulfonate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of 1,3-benzodioxol-5-yl 4-methylbenzenesulfonate

Chemical Property:

PSA：70.21000
LogP:3.57220

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 1,3-benzodioxol-5-yl 4-methylbenzenesulfonate

There total 3 articles about 1,3-benzodioxol-5-yl 4-methylbenzenesulfonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 533-31-3
Sesamol

: 455-16-3
p-toluenesulfonyl fluoride

: 16387-85-2
benzo[d][1,3]dioxol-5-yl 4-methylbenzenesulfonate

Guidance literature:: With N,N,N′,N′-tetramethyl-N″-tert-butylguanidine; 1,1,1,3,3,3-hexamethyl-disilazane; In acetonitrile; at 20 ℃; for 0.166667h;
DOI:10.1002/anie.202112375

Reference yield: 84.0%

: 533-31-3
Sesamol

: 98-59-9
p-toluenesulfonyl chloride

: 16387-85-2
benzo[d][1,3]dioxol-5-yl 4-methylbenzenesulfonate

Guidance literature:: With triethylamine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1021/ja711449e

Reference yield:

: 120-57-0,30024-74-9
piperonal

: 16387-85-2
benzo[d][1,3]dioxol-5-yl 4-methylbenzenesulfonate

Guidance literature:: Multi-step reaction with 2 steps

1: peroxyacetic acid; acetic acid; toluene-4-sulfonic acid / Erwaermen des Reaktionsgemisches mit aethanol. Kalilauge

2: aq. NaOH solution

With peracetic acid; sodium hydroxide; toluene-4-sulfonic acid; acetic acid;
DOI:10.1007/BF03019874