Phosphoric acid, diethyl (2E)-3-(4-methylphenyl)-2-propenyl ester

Base Information

Chemical Name:Phosphoric acid, diethyl (2E)-3-(4-methylphenyl)-2-propenyl ester
CAS No.:164527-43-9
Molecular Formula:C14H21O4P
Molecular Weight:284.292
Hs Code.:
Mol file:164527-43-9.mol

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Chemical Property of Phosphoric acid, diethyl (2E)-3-(4-methylphenyl)-2-propenyl ester

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Technology Process of Phosphoric acid, diethyl (2E)-3-(4-methylphenyl)-2-propenyl ester

There total 4 articles about Phosphoric acid, diethyl (2E)-3-(4-methylphenyl)-2-propenyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 122058-30-4
p-methylcinnamyl alcohol

: 814-49-3
diethyl chlorophosphate

: 164527-43-9
phosphoric acid diethyl ester 3-p-tolylallyl ester

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 0 ℃; for 4h; Inert atmosphere; Schlenk technique;
DOI:10.1021/acs.joc.8b02432

Reference yield:

: 97585-04-1,20511-20-0,24393-49-5
ethyl (E)-3-(4-methylphenyl)acrylate

: 164527-43-9
phosphoric acid diethyl ester 3-p-tolylallyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: diisobutylaluminium hydride / dichloromethane / 2 h / 20 °C

2: dmap; triethylamine / dichloromethane / 4 h / 0 °C / Inert atmosphere; Schlenk technique

With dmap; diisobutylaluminium hydride; triethylamine; In dichloromethane;
DOI:10.1021/acs.joc.8b02432

Reference yield:

: 104-87-0
4-methyl-benzaldehyde

: 164527-43-9
phosphoric acid diethyl ester 3-p-tolylallyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: methylmagnesium bromide / tetrahydrofuran / 0.25 h / 20 °C

1.2: 4 h / Reflux

2.1: diisobutylaluminium hydride / dichloromethane / 2 h / 20 °C

3.1: dmap; triethylamine / dichloromethane / 4 h / 0 °C / Inert atmosphere; Schlenk technique

With dmap; methylmagnesium bromide; diisobutylaluminium hydride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/acs.joc.8b02432