4,4-bis(dimethylphenylphosphine)-arachno-4-platinanonaborane

Base Information

Chemical Name:4,4-bis(dimethylphenylphosphine)-arachno-4-platinanonaborane
CAS No.:78520-19-1
Molecular Formula:C₁₆H₃₄B₈P₂Pt
Molecular Weight:569.961
Hs Code.:

Synonyms:

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Chemical Property of 4,4-bis(dimethylphenylphosphine)-arachno-4-platinanonaborane

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Technology Process of 4,4-bis(dimethylphenylphosphine)-arachno-4-platinanonaborane

There total 4 articles about 4,4-bis(dimethylphenylphosphine)-arachno-4-platinanonaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 4.1%

: 15393-14-3
cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)]

: 98514-25-1
6-hydroxy-nido-decaborane

: 73588-96-2
bis(dimethylphosphine)-di-μ-(2,3,4-η3-nido-hexaboranyl)-diplatinum

: 78520-19-1
4,4-bis(dimethylphenylphosphine)-arachno-4-platinanonaborane

Guidance literature:: In diethyl ether; dichloromethane; under N2, a mixt. of 1 equiv of Pt-complex and 2 equiv of B10H13OH in CH2Cl2-Et2O was stirred for ca. 72 h at room temp.; filtered through silica gel, washed through with light petroleum, volatile components removed under reduced pressure, products sepd. by preparative scale t.l.c. with light petroleum as eluant, Pt2(B6H9)(PMe2Ph)2 recrystd. from CH2Cl2-C6H12;
DOI:10.1039/DT9850000953

Reference yield: 3.6%

: 15393-14-3
cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)]

: 17702-42-0
6,6'-bis(nido-decaboranyl) oxide

: 73588-96-2
bis(dimethylphosphine)-di-μ-(2,3,4-η3-nido-hexaboranyl)-diplatinum

: 78520-19-1
4,4-bis(dimethylphenylphosphine)-arachno-4-platinanonaborane

: 7,7-bis(dimethylphenylphosphine)-nido-7-platinaundecaborane

Guidance literature:: In diethyl ether; dichloromethane; under N2, a soln. of equimolar amt. of Pt-complex and (B10H13)2O in CH2Cl2-Et2O was stirred at 20°C for 72 h; filtered through silica gel, washed through with light petroleum, volatile components removed under reduced pressure, products sepd. by preparative scale t.l.c. with light petroleum as eluant, Pt2(B6H9)2(PMe2Ph)2 recrystd. from CH2Cl2-C6H12; elem. anal.;
DOI:10.1039/DT9850000953

Reference yield: 1.0%

: 15393-14-3
cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)]

: N(CH₃)4⁽¹⁺⁾*B₉H₁₄^(1-)=(N(CH₃)4)(B₉H₁₄)

: 73588-96-2
bis(dimethylphosphine)-di-μ-(2,3,4-η3-nido-hexaboranyl)-diplatinum

: 78520-19-1
4,4-bis(dimethylphenylphosphine)-arachno-4-platinanonaborane

Guidance literature:: In methanol; byproducts: B(OMe)3; under N2, a soln. of 1 equiv of (NMe4)(B9H14) in MeOH was mixed with a soln. of 1 equiv of Pt-complex in MeOH, 1 h; the ppt. filtered off ((PhMe2P)2PtB8H12), the liquor reduced in volume under reduced pressure, sepd. by preparative scale t.l.c. (light petroleum-CH2Cl2), the combined fractions of (PhMe2P)2PtB8H12 recrystd. from CH2Cl2-C6H12;
DOI:10.1039/DT9850000953