{Pt2(μ-η3-B6H9)(μ-(η3-B6H8.-eta.2-{PtH-cis-(PMe2Ph)2}))(PMe2Ph)2}

Base Information

• Chemical Name: {Pt2(μ-η3-B6H9)(μ-(η3-B6H8.-eta.2-{PtH-cis-(PMe2Ph)2}))(PMe2Ph)2}
• CAS No.: 98523-10-5
• Molecular Formula: C₃₂H₆₂B₁₂P₄Pt₃
• Molecular Weight: 1285.71
• Mol file: 98523-10-5.mol

Synonyms:

Chemical Property of {Pt2(μ-η3-B6H9)(μ-(η3-B6H8.-eta.2-{PtH-cis-(PMe2Ph)2}))(PMe2Ph)2}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Pt2(μ-η3-B6H9)(μ-(η3-B6H8.-eta.2-{PtH-cis-(PMe2Ph)2}))(PMe2Ph)2}

There total 1 articles about {Pt2(μ-η3-B6H9)(μ-(η3-B6H8.-eta.2-{PtH-cis-(PMe2Ph)2}))(PMe2Ph)2} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)] (15393-14-3) + bis(dimethylphosphine)-di-μ-(2,3,4-η3-nido-hexaboranyl)-diplatinum (73588-96-2) + N,N,N',N'-tetramethyl-1,8-diaminonaphthalene (20734-58-1) → {Pt2(μ-η3-B6H9)(μ-(η3-B6H8.-eta.2-{PtH-cis-(PMe2Ph)2}))(PMe2Ph)2} (98523-10-5)

Guidance literature:

In tetrahydrofuran; dichloromethane; under N2, CH2Cl2-THF was distd. to 1 equiv of Pt2(B6H9)2(PMe2Ph)2 at -196°C, 1 equiv of C10H6(N(CH3)2)2 was added, warmed to room temp., after ca. 15 min 1 equiv of PtCl2(PMe2Ph) was added, heated under reflux for ca. 1 h; solvent removed under reduced pressure, the residue extd. with CH2Cl2, sepd. by preparative scale t.l.c. with light petroleum-CH2Cl2 as eluant;

DOI:10.1039/DT9850000953

upstream raw materials:

cis-[bis(dimethylphenylphosphane)dichlroplatinum(II)]

bis(dimethylphosphine)-di-μ-(2,3,4-η3-nido-hexaboranyl)-diplatinum

N,N,N',N'-tetramethyl-1,8-diaminonaphthalene