cis-bis(6-endo-diphenylphosphinooxybicyclo[3.2.0]hept-2-enyl)palladium(II) chloride

Base Information

• Chemical Name: cis-bis(6-endo-diphenylphosphinooxybicyclo[3.2.0]hept-2-enyl)palladium(II) chloride
• CAS No.: 1000295-22-6
• Molecular Formula: C₃₈H₃₈Cl₂O₂P₂Pd
• Molecular Weight: 765.992
• Mol file: 1000295-22-6.mol

Synonyms:

Chemical Property of cis-bis(6-endo-diphenylphosphinooxybicyclo[3.2.0]hept-2-enyl)palladium(II) chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-bis(6-endo-diphenylphosphinooxybicyclo[3.2.0]hept-2-enyl)palladium(II) chloride

There total 1 articles about cis-bis(6-endo-diphenylphosphinooxybicyclo[3.2.0]hept-2-enyl)palladium(II) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trans-bis(6-endo-diphenylphosphinooxybicyclo[3.2.0]hept-2-enyl)palladium(II) chloride (1000295-22-6) → [Pd((PPh2O)(PPh2OH)(μ-Cl)]2 + cis-bis(6-endo-diphenylphosphinooxybicyclo[3.2.0]hept-2-enyl)palladium(II) chloride (1000295-22-6)

Guidance literature:

In chloroform-d1; under N2 or Ar; dissolved in CDCl3; mixt. of three Pd complexes in soln.obtained; stored over activated molecular sieves; solid recrystd. by layering concd. CH2Cl2 soln. with hexane-ether at 25°C over 2 d (di-Pd complex isolated);

DOI:10.1016/j.jorganchem.2005.01.037

Reference yield:

trans-bis(6-endo-diphenylphosphinooxybicyclo[3.2.0]hept-2-enyl)palladium(II) chloride (1000295-22-6) → [Pd((PPh2O)(PPh2OH)(μ-Cl)]2 + cis-bis(6-endo-diphenylphosphinooxybicyclo[3.2.0]hept-2-enyl)palladium(II) chloride (1000295-22-6)

Guidance literature:

In chloroform-d1; under N2 or Ar; dissolved in CDCl3; mixt. of three Pd complexes in soln.obtained; stored over activated molecular sieves; solid recrystd. by layering concd. CH2Cl2 soln. with hexane-ether at 25°C over 2 d (di-Pd complex isolated);

DOI:10.1016/j.jorganchem.2005.01.037