Propanal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2R)-

Base Information

Chemical Name:Propanal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2R)-
CAS No.:167468-64-6
Molecular Formula:C19H24O2Si
Molecular Weight:312.484
Hs Code.:
DSSTox Substance ID:DTXSID40446600
Nikkaji Number:J703.705H
Wikidata:Q82265309
Mol file:167468-64-6.mol

Synonyms:Propanal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2R)-;167468-64-6;DTXSID40446600;(R)-2-(tert-Butyldiphenylsiloxy)propanal

Suppliers and Price of Propanal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2R)-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of Propanal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2R)-

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:6
Exact Mass:312.154556538
Heavy Atom Count:22
Complexity:331

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C=O)O[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C(C)(C)C
Isomeric SMILES:C[C@H](C=O)O[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C(C)(C)C

Technology Process of Propanal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2R)-

There total 3 articles about Propanal, 2-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2R)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 561038-05-9
(R)-2-(tert-butyldiphenylsilanyloxy)propionic acid methyl ester

: 167468-64-6
(2R)-2-(tert-butyldiphenylsiloxy)propanal

Guidance literature:: (R)-2-(tert-butyldiphenylsilanyloxy)propionic acid methyl ester; With diisobutylaluminium hydride; In hexane; toluene; at -78 ℃; for 1.5h;

With methanol; In hexane; toluene; at -78 ℃; for 0.25h;
DOI:10.1021/jo502198y

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 167468-64-6
(2R)-2-(tert-butyldiphenylsiloxy)propanal

Guidance literature:: Multi-step reaction with 2 steps

1: 100 percent / Et₃N; DMAP / CH₂Cl₂ / 22 h / 0 °C

2: DIBAL-H / toluene / 1.5 h / -78 °C

With dmap; diisobutylaluminium hydride; triethylamine; In dichloromethane; toluene;
DOI:10.1021/ol050763x

Reference yield:

: (2S,2'R/S)-(-)-<2-(tert-Butyldiphenylsilyloxy)propylidene>-(2-methoxymethylpyrrolidin-1-yl)amine

: 87696-33-1
(S)-2-(O-tert-butyldiphenylsilyloxy)propanal

: 167468-64-6
(2R)-2-(tert-butyldiphenylsiloxy)propanal

Guidance literature:: With ozone; In dichloromethane; Petroleum ether; at -78 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;