2-(Trimethylsilyl)biphenyl

Base Information

• Chemical Name: 2-(Trimethylsilyl)biphenyl
• CAS No.: 17049-39-7
• Molecular Formula: C15H18Si
• Molecular Weight: 226.393
• European Community (EC) Number: 811-996-9
• DSSTox Substance ID: DTXSID50375371
• Nikkaji Number: J408.811E
• Wikidata: Q82163902
• Mol file: 17049-39-7.mol

Synonyms:2-(Trimethylsilyl)biphenyl;17049-39-7;[1,1'-Biphenyl]-2-yltrimethylsilane;Trimethyl-(2-phenylphenyl)silane;2-Trimethylsilylbiphenyl;DTXSID50375371;AKOS022173017;FT-0754496;F72200

Chemical Property of 2-(Trimethylsilyl)biphenyl

Chemical Property:

• Melting Point: 37.4 °C(Solv: ethanol (64-17-5))
• Boiling Point: 133-134 °C(Press: 7 Torr)
• PSA: 0.00000
• Density: 0.96±0.1 g/cm3(Predicted)
• LogP: 3.89880
• Storage Temp.: 2-8°C
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 2
• Exact Mass: 226.117777109
• Heavy Atom Count: 16
• Complexity: 210

Purity/Quality:

99% ^*data from raw suppliers

[1,1'-Biphenyl]-2-yltrimethylsilane 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C)C1=CC=CC=C1C2=CC=CC=C2

Technology Process of 2-(Trimethylsilyl)biphenyl

There total 1 articles about 2-(Trimethylsilyl)biphenyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

trimethylsilyl trifluoromethanesulfonate (27607-77-8) + 2,3-dibromobenzene (583-53-9) → C21H22Si + 9,9-dimethyl-9-silafluorene (13688-68-1) + trimethylphenylsilane (768-32-1) + 1-phenyl-2-(trimethylsilyl)benzene (17049-39-7)

Guidance literature:

2,3-dibromobenzene; With tert.-butyl lithium; In tetrahydrofuran; diethyl ether; pentane; at -120 - 20 ℃; for 0.666667h;

trimethylsilyl trifluoromethanesulfonate; In tetrahydrofuran; diethyl ether; pentane; at -120 - -110 ℃; for 0.5h; Further stages. Further byproducts.;

DOI:10.1021/jo7013033

upstream raw materials:

trimethylsilyl trifluoromethanesulfonate

2,3-dibromobenzene

Refernces