1,3,5-Triphosphorin, 2,4,6-tris(1,1-dimethylethyl)-

Base Information

• Chemical Name: 1,3,5-Triphosphorin, 2,4,6-tris(1,1-dimethylethyl)-
• CAS No.: 173166-52-4
• Molecular Formula: C15H27P3
• Molecular Weight: 300.301
• DSSTox Substance ID: DTXSID40448563
• Nikkaji Number: J1.024.148K
• Wikidata: Q82267614
• Mol file: 173166-52-4.mol

Synonyms:1,3,5-Triphosphorin, 2,4,6-tris(1,1-dimethylethyl)-;173166-52-4;DTXSID40448563;Tri-tert-butyl-1,3,5-triphosphorin;2,4,6-tri-t-butyl-1,3,5-triphosphabenzene

Chemical Property of 1,3,5-Triphosphorin, 2,4,6-tris(1,1-dimethylethyl)-

Chemical Property:

• XLogP3: 1.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 300.13256185
• Heavy Atom Count: 18
• Complexity: 321

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)(C)C1=PC(=PC(=P1)C(C)(C)C)C(C)(C)C

Technology Process of 1,3,5-Triphosphorin, 2,4,6-tris(1,1-dimethylethyl)-

There total 2 articles about 1,3,5-Triphosphorin, 2,4,6-tris(1,1-dimethylethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

2,2-dimethylpropylidynephosphine (78129-68-7) → 2,4,6-tri-tert-butyl-1,3,5-triphosphinine (173166-52-4)

Guidance literature:

With tert-butylimidovanadium(V) trichloride; In toluene; at -78 - 25 ℃;

Reference yield:

2,2-dimethylpropylidynephosphine (78129-68-7) + 1-adamantylphosphaacetylene (101055-70-3) → 2,4,6-tri-tert-butyl-1,3,5-triphosphinine (173166-52-4) + 6-(1-Adamantyl)-2,4-di-tert-butyl-1,3,5-triphosphabenzene

Guidance literature:

1-adamantylphosphaacetylene; With tert-butylimidovanadium(V) trichloride; In toluene; at -78 - 25 ℃;

2,2-dimethylpropylidynephosphine; In toluene; at -78 - 25 ℃; Further stages. Title compound not separated from byproducts.;

DOI:10.1002/1521-3765(20001215)6:24<4558::AID-CHEM4558>3.0.CO;2-6

Reference yield: 98.0%

2,2-dimethylpropylidynephosphine (78129-68-7) + 2,4,6-tri-tert-butyl-1,3,5-triphosphinine (173166-52-4) → 2,4,6,7-Tetra-tert-butyl-1,3,5,8-tetraphospha-bicyclo[2.2.2]octa-2,5,7-triene (161689-77-6)

Guidance literature:

DOI:10.1002/cber.19971300703

upstream raw materials:

2,2-dimethylpropylidynephosphine

1-adamantylphosphaacetylene

Downstream raw materials:

2,4,6,7-Tetra-tert-butyl-1,3,5,8-tetraphospha-bicyclo[2.2.2]octa-2,5,7-triene