1,2-Epoxyundecane

Base Information

• Chemical Name: 1,2-Epoxyundecane
• CAS No.: 17322-97-3
• Molecular Formula: C₁₁H₂₂O
• Molecular Weight: 170.295
• Mol file: 17322-97-3.mol

Synonyms:1,2-Epoxyundecane;2-nonyl-oxirane;1-undecene oxide;Oxirane,nonyl;nonyloxirane;

Chemical Property of 1,2-Epoxyundecane

Chemical Property:

• Boiling Point: 105 °C(Press: 12 Torr)
• PSA: 12.53000
• Density: 0.8415 g/cm3
• LogP: 3.52590

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,2-Epoxyundecane

There total 9 articles about 1,2-Epoxyundecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1-undecene (821-95-4) → 1,2-epoxyundecane (17322-97-3,149948-91-4,123493-71-0)

Guidance literature:

With [(C₁₈H₃₇)₂(CH₃)₂N]₃[SiO₄H(WO₅)₃]; dihydrogen peroxide; In ethyl acetate; at 59.84 ℃; for 3h;

DOI:10.1039/c4ra04036h

Reference yield: 92.0%

(+/-)-1-chloro-2-tridecanol (139926-09-3) → 1,2-epoxyundecane (17322-97-3,149948-91-4,123493-71-0)

Guidance literature:

With potassium hydroxide; In diethyl ether; for 6h;

DOI:10.1016/j.tetasy.2013.02.005

Reference yield: 90.0%

caprinaldehyde (112-31-2) + trimethylsulfoxonium iodide (1774-47-6) → 1,2-epoxyundecane (17322-97-3,149948-91-4,123493-71-0)

Guidance literature:

With potassium tert-butylate; In dimethyl sulfoxide; for 16h; Ambient temperature;

upstream raw materials:

caprinaldehyde

trimethylsulfoxonium iodide

1-undecene

diazomethane

Downstream raw materials:

(R)-(+)-1,2-epoxyundecane

undecyl alcohol

undecan-2-ol

fellutamide B

Refernces

• 1、 Kim, Soohyung,Jeong, Ha Young,Kim, Seonghan,Kim, Hongsik,Lee, Sojeong,Cho, Jaeheung,Kim, Cheal,Lee, Dongwhan. "Proton Switch in the Secondary Coordination Sphere to Control Catalytic Events at the Metal Center: Biomimetic Oxo Transfer Chemistry of Nickel Amidate Complex". supporting information. p. 4700 - 4708. Retrieved 2021/02/12.
• 2、 Jeong, Ah Rim,Shin, Jong Won,Jeong, Jong Hwa,Bok, Kwon Hee,Kim, Cheal,Jeong, Donghyun,Cho, Jaeheung,Hayami, Shinya,Min, Kil Sik. "Dinuclear Iron(III) and Nickel(II) Complexes Containing N-(2-Pyridylmethyl)-N′-(2-hydroxyethyl)ethylenediamine: Catalytic Oxidation and Magnetic Properties". . p. 3023 - 3033. Retrieved 2017/03/13.