Technology Process of Diiodo(phenyl)borane
There total 17 articles about Diiodo(phenyl)borane which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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In
dichloromethane;
byproducts: ISi(CH3)3; in inert atmosphere, dropwise addn. of trimethylphenylsilane to a stirred soln. of BI3 at -78°C, stirring (-78°C, 1 h), slow warming to room temp.; evapn. in vac. at 30°C, distn.;
- Guidance literature:
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byproducts: I2; warming at 120°C for 16 h; sublimation of I2 in vac., distn.;
- Guidance literature:
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BI3 and Sn(C6H5)4 melt in exothermic react.; stirring for 24 h at 140-150° C; slow distn.;