Li⁽¹⁺⁾*Pd(CH₃)3P(C₂H₅)2C₆H₅^(1-)=Li(Pd(CH₃)3P(C₂H₅)2C₆H₅)

Base Information

• Chemical Name: Li⁽¹⁺⁾*Pd(CH₃)3P(C₂H₅)2C₆H₅^(1-)=Li(Pd(CH₃)3P(C₂H₅)2C₆H₅)
• CAS No.: 83947-24-4
• Molecular Formula: C₁₃H₂₄PPd*Li
• Molecular Weight: 324.668
• Mol file: 83947-24-4.mol

Synonyms:

Chemical Property of Li⁽¹⁺⁾*Pd(CH₃)3P(C₂H₅)2C₆H₅^(1-)=Li(Pd(CH₃)3P(C₂H₅)2C₆H₅)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of Li⁽¹⁺⁾*Pd(CH₃)3P(C₂H₅)2C₆H₅^(1-)=Li(Pd(CH₃)3P(C₂H₅)2C₆H₅)

There total 1 articles about Li⁽¹⁺⁾*Pd(CH₃)3P(C₂H₅)2C₆H₅^(1-)=Li(Pd(CH₃)3P(C₂H₅)2C₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

sodium tetrachloropalladate(II) + methyllithium (917-54-4) + diethyl-phenyl-phosphine (1605-53-4) → Li(1+)*Pd(CH3)3P(C2H5)2C6H5(1-)=Li(Pd(CH3)3P(C2H5)2C6H5) (83947-24-4) + dilithium tetramethylpalladate(II) (83947-30-2) + cis-PdMe2(PEt2Ph)2 (77881-04-0)

Guidance literature:

In diethyl ether; byproducts: LiCl; PEt2Ph was added under inert atmosphere to a suspn. of Na2PdCl4 in Et2O, resulting ppt. of PdCl2(PEt2Ph)2 was treated without isolation with anether soln. of MeLi at room temp.; not isolated from the soln.; (1)H NMR spectral data;

DOI:10.1021/om00074a007

upstream raw materials:

methyllithium

diethyl-phenyl-phosphine