1-Chloro-4-[(Z)-phenyl-ONN-azoxy]benzene

Base Information

• Chemical Name: 1-Chloro-4-[(Z)-phenyl-ONN-azoxy]benzene
• CAS No.: 17478-82-9
• Molecular Formula: C₁₂H₉ClN₂O
• Molecular Weight: 232.669
• DSSTox Substance ID: DTXSID10512841
• Mol file: 17478-82-9.mol

Synonyms:17478-82-9;1-Chloro-4-[(Z)-phenyl-ONN-azoxy]benzene;DTXSID10512841

Chemical Property of 1-Chloro-4-[(Z)-phenyl-ONN-azoxy]benzene

Chemical Property:

• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 232.0403406
• Heavy Atom Count: 16
• Complexity: 243

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)[N+](=NC2=CC=C(C=C2)Cl)[O-]

Technology Process of 1-Chloro-4-[(Z)-phenyl-ONN-azoxy]benzene

There total 2 articles about 1-Chloro-4-[(Z)-phenyl-ONN-azoxy]benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 3.0%

4-chloroazobenzene (4340-77-6) → 4-chloro-2'-heptafluoropropylazobenzene (144499-67-2) + 4-chloro-4'-heptafluoropropylazobenzene (144499-66-1) + β-p-chloroazoxybenzene (17478-82-9,43187-54-8) + 4,4'-dichloroazoxybenzene (43187-53-7,81701-79-3,127838-76-0)

Guidance literature:

With (C₃F₇CO₂)2; In dichloromethane; 1,1,2-Trichloro-1,2,2-trifluoroethane; at 0 ℃; for 8h; Yield given. Title compound not separated from byproducts;

DOI:10.1016/S0022-1139(00)82833-X

Reference yield:

→ β-p-chloroazoxybenzene (17478-82-9,43187-54-8)

Guidance literature:

4-Chlor-azobenzol, 1) hν, 2) AcOH, H2O2, CHCl3;

DOI:10.1021/ja01066a025

Reference yield:

β-p-chloroazoxybenzene (17478-82-9,43187-54-8) → 2-(4-chloro-phenylazo)-phenol (21737-17-7)

Guidance literature:

With antimonypentachloride; Yield given. Multistep reaction; 1.) CCl₄, overnight; 2.) nitrobenzene, 180-181 deg C, 2 h;

DOI:10.1016/0040-4020(80)80162-1

upstream raw materials:

4-chloroazobenzene

Downstream raw materials:

2-(4-chloro-phenylazo)-phenol