Benzenamine, N-[[4-(1-methylethyl)phenyl]methylene]-

Base Information

• Chemical Name: Benzenamine, N-[[4-(1-methylethyl)phenyl]methylene]-
• CAS No.: 17693-88-8
• Molecular Formula: C16H17N
• Molecular Weight: 223.318
• DSSTox Substance ID: DTXSID50402792
• Nikkaji Number: J1.625.022H
• Mol file: 17693-88-8.mol

Synonyms:Benzenamine, N-[[4-(1-methylethyl)phenyl]methylene]-;17693-88-8;SCHEMBL9805126;DTXSID50402792;N-(4-Isopropylbenzylidene)aniline;AKOS024405137;N-[(E)-(4-isopropylphenyl)methylidene]aniline

Chemical Property of Benzenamine, N-[[4-(1-methylethyl)phenyl]methylene]-

Chemical Property:

• XLogP3: 3.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 3
• Exact Mass: 223.136099547
• Heavy Atom Count: 17
• Complexity: 230

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC(C)C1=CC=C(C=C1)C=NC2=CC=CC=C2

Technology Process of Benzenamine, N-[[4-(1-methylethyl)phenyl]methylene]-

There total 5 articles about Benzenamine, N-[[4-(1-methylethyl)phenyl]methylene]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

aniline (62-53-3) + cuminol (536-60-7) → N-(4-isopropylbenzylidene)benzenamine (17693-88-8)

Guidance literature:

With CeO₂ nanorods anchored on mesoporous carbon; air; In toluene; at 80 ℃; for 2h; under 760.051 Torr;

DOI:10.1039/c6cc05496j

Reference yield: 80.0%

cuminol (536-60-7) + Azobenzene (1227476-15-4) → N-(4-isopropylbenzylidene)benzenamine (17693-88-8)

Guidance literature:

With Ni/HT; In toluene; at 140 ℃; for 15h; Autoclave; Inert atmosphere;

Reference yield: 72.0%

aniline (62-53-3) + cuminol (536-60-7) → N-(4-isopropylbenzylidene)benzenamine (17693-88-8) + N-(4-isopropylbenzyl)benzenamine (81308-22-7)

Guidance literature:

With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; 1-(2,2-dimethoxyethyl)-3-(propyl-3-sulfonate)benzimidazoluim; potassium tert-butylate; In neat (no solvent); at 120 ℃; for 24h; Schlenk technique; Sealed tube;

DOI:10.1016/j.catcom.2015.10.028

upstream raw materials:

aniline

cuminol

Azobenzene

4-methylisopropylbenzene

Downstream raw materials:

2-(4-isopropylphenyl)-2-(phenylamino)acetonitrile

N-(4-isopropylbenzyl)benzenamine

2-[4-(4-isopropyl-trans-styryl)-phenyl]-5-phenyl-oxazole

trans-4,4'-Bis-(4-isopropyl-styryl)-biphenyl